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Key concepts. Organic chemistry is the study of carbon compoundsCarbon atoms can form diverse molecules by bonding to four other atomsA small number of chemical groups are key to the functioning of biological molecules. Organic chemistry is the study of carbon compounds. The term
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1. Carbon: The backbone of life
3. Organic chemistry is the study of carbon compounds The term “organic” chemistry came from the misconception that carbon-based compounds were always connected to life
4. Organic chemistry is the study of carbon compounds The term “organic” chemistry came from the misconception that carbon-based compounds were always connected to life
Exception:
5. Organic chemistry is the study of carbon compounds Exception:
6. Organic chemistry is the study of carbon compounds It mostly involves CHOPNS
With few elements it is possible to create a diversity of molecules
….because of the special properties of carbon
7. Carbon atoms can form diverse molecules by bonding to four other atoms
8. Carbon atoms can form diverse molecules by bonding to four other atoms The key to an atom’s chemical characteristics is its electron configuration
Carbon’s valence shell is half-full…or is it half-empty?
9. Carbon atoms can form diverse molecules by bonding to four other atoms Carbon usually completes its valence shell by sharing electrons with other atoms in covalent bonds
10. Carbon atoms can form diverse molecules by bonding to four other atoms Carbon usually completes its valence shell by sharing electrons with other atoms in covalent bonds ..
11. Carbon atoms can form diverse molecules by bonding to four other atoms Carbon usually completes its valence shell by sharing electrons with other atoms in covalent bonds
12. Carbon atoms can form diverse molecules by bonding to four other atoms Carbon usually completes its valence shell by sharing electrons with other atoms in covalent bonds
13. Carbon atoms can form diverse molecules by bonding to four other atoms
14. Carbon atoms can form diverse molecules by bonding to four other atoms
15. Molecular diversity arising from carbon skeleton variation
16. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
17. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
18. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
19. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
Branching
,
,
20. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
Branching
Double bonds
21. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
Branching
Double bonds
22. Molecular diversity arising from carbon skeleton variation Sources of diversity:
Chain length
Branching
Double bonds
Ring formation
23. Molecular diversity arising from carbon skeleton variation
24. Other forms of diversity
25. Other forms of diversity Isomers-compounds that have the same numbers of atoms of the same elements, but different structures (hence different properties)
26. Other forms of diversity Three types of isomers
Structural
Geometric
Enantiomers
27. Other forms of diversity Three types of isomers
Structural isomers differ in the arrangement of their atoms or in the arrangement of double bonds
28. Other forms of diversity Three types of isomers
Structural isomers differ in the arrangement of their atoms or in the arrangement of double bonds
29. Other forms of diversity Three types of isomers
Structural isomers differ in the arrangement of their atoms or in the arrangement of double bonds
30. Other forms of diversity Three types of isomers
Structural isomers differ in the arrangement of their atoms or in the presence or absence of double bonds
31. Other forms of diversity Three types of isomers
Structural
Geometric isomers have the same covalent partnerships, but differ in their spatial arrangement (related to inflexibility of double bonds)
32. Other forms of diversity Three types of isomers
Structural
Geometric isomers have the same covalent partnerships, but differ in their spatial arrangement (related to inflexibility of double bonds)
33. Other forms of diversity Three types of isomers
Structural
Geometric
Enantiomers are isomers that are mirror images of each other
34. A small number of chemical functional groups are key to the function of biological molecules We’ve been focusing on the carbon skeleton….what’s attached impacts form and functionWe’ve been focusing on the carbon skeleton….what’s attached impacts form and function
35. A small number of chemical functional groups are key to the function of biological molecules Properties of the molecule will also depend on the molecular components attached to the carbon skeleton
Functional groups can replace H
These groups participate in chemical reactions and change the molecular shape
36. A small number of chemical functional groups are key to the function of biological molecules
37. Can you identify any of the common functional groups on the following biological molecules? Starch and celluloseStarch and cellulose
38. Can you identify any of the common functional groups on the following biological molecules?
39. Can you identify any of the common functional groups on the following biological molecules?
40. Can you identify any of the common functional groups on the following biological molecules?
41. Can you identify any of the common functional groups on the following biological molecules?