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Types Of Chemical Reactions. Objective. Distinguish between the 5 different types of reactions Predict the products of a reaction Predict the physical states of products. 5 Types of Reactions. Composition/Synthesis Decomposition Single Replacement Double Replacement Combustion.
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Objective • Distinguish between the 5 different types of reactions • Predict the products of a reaction • Predict the physical states of products
5 Types of Reactions • Composition/Synthesis • Decomposition • Single Replacement • Double Replacement • Combustion
Composition Reactions aka synthesis rxn • When two or more substances react to form a single product • 2 reactants → 1 product • A + X → AX • H2 + O2 → • MgO + CO2 → 2 H2O MgCO3
Decomposition • Occurs when a compound is broken down into simpler substances • Single reactant yields two or more products • (1 reactant → 2 products) • forms a common gas as one of the products; CO2, O2, SO2, H2O
Decomposition Examples • AX → A+ X • HgO → • CaCO3 → Hg + O2 CaO + CO2
Single Replacement • One substance replaces another • A metal replaces a metal, if it is more active • A non-metal replaces a non-metal, if it is more active
Single Replacement Examples • A and B are metals; X and Y are non-metals A + BX → AX + B OR Y + BX → BY + X • Mg + Zn(NO3)2 → • Cl2 + KBr → Mg (NO3)2 + Zn KCl + Br2
Double Replacement • An exchange of partners • The metal replaces the metal and the non-metal replaces the non-metal • AX + BY → AY + BX • Na2S + Cd(NO3)2 → • BaCl2 + K2CO3 → NaNO3 + CdS BaCO3 + KCl
Composition • Two elements or compounds combine to form a single substance • A + X → • Fe + O2 → • H2O + SO3 → AX FeO H2 SO4
5 Kinds of Decomposition Reactions • Metallic Carbonates • Metallic Hydroxides • Metallic Chlorates • Oxy Acids • Oxides
Metallic Carbonates • CaCO3→ • Metal oxide and carbon dioxide formed CaO + CO2
Metallic Hydroxides • Many metallic hydroxides (OH-), when heated, decompose into metallic oxides and water. • Ca(OH)2 → • Metal oxide and water formed • Exceptions to the rule: NaOH and KOH CaO + H20
Metallic Chlorates • (ClO3-), when heated, decompose into metallic chlorides and oxygen • 2KClO3→ • metal chloride and oxygen formed 2KCl + 3O2
Oxy Acids • Some oxy acids, when heated, decompose into nonmetallic oxides and water • Seltzer Water • H2CO3 → • Acid Rain • H2SO3 → CO2 + H2O SO2 + H2O
Oxides • Some oxides, when heated, decompose. • 2HgO → • 2Pb O2 → 2Hg + O2 2PbO + O2
4 Kinds of Single Replacement Reactions • Metal w/ more active metal • Hydrogen in acids w/ more active metal • Hydrogen in water w/ by most active metals • Halogen w/ more active halogen
Metal w/ more active Metal • Replacement of a metal in a compound by a more active metal (PCS Mazintl) • Zn + CuSO4 → • Zinc replaces the copper, therefore zinc is more active ZnSO4 + Cu (s)
Hydrogen in acids w/ more active metals • Replacement of hydrogen, in acids, by metals more active than hydrogen (PCS Mazintl) • Zn + H2SO4 → • The corresponding metallic compound and hydrogen gas are formed Zn SO4 + H2 (g)
Hydrogen in water w/ most active metals • Replacement of hydrogen, in water, by the most active metals. Which Metals? • All Group I and some of Group II • Ca + 2 H2O → • A hydroxide and hydrogen gas are formed Ca(OH)2 + H2 (g)
Halogen w/ more active halogen • Replacement of a halogen by a more active halogen • Cl2 + 2 KBr → • Br2 + 2 KI → • MgBr2 + I2 → • The corresponding metallic compound and elemental halogen are formed 2 KCl + Br2 2 KBr + I2 no reaction because Br is more active than I, so I will not replace Br
Activity Series of the elements • A + BX → AX + B • If A replaces B, then A is more active than B • If an element is above another element on the chart, then it is more active, and will replace the lower positioned element • All metals above hydrogen displace hydrogen from hydrochloric acid or dilute sulfuric acid.
P.C.S. MazintlActivity of Halogens P potassium Fluorine C calcium Chlorine S sodium Bromine M magnesium Iodine a aluminum z zinc i iron n nickel t tin l lead HYDROGEN Copper Mercury Silver More Active
Example • Zn (s) + CuSO4 (aq)→
P.C.S. MazintlActivity of Halogens P potassium Fluorine C calcium Chlorine S sodium Bromine M magnesium Iodine a aluminum z zinc i iron n nickel t tin l lead HYDROGEN Copper Mercury Silver More Active
Example • Zn (s) + CuSO4 (aq)→ • Mg (s) + Zn(NO3)2 (aq) → ZnSO4 (aq) + Cu (s) Mg (NO3)2 (aq) + Zn (s)
Double Replacement • AX + BY → AY + BX • usually takes place in a solution of water…all reactant solutions are aqueous • 2 compounds → 2 different compounds • 1 of these will not be soluble in water…solid (s) • The soluble (dissolved) compound is aqueous…(aq) • In order for you to know if the reaction has occurred, a solid or gas must form • 1 product will typically be: • solid: precipitate • gas: CO2 SO2 NH3
Solubility Rules for Double Dis(RE)placement Reactions • How to determine which product is the precipitate Na+ K+ NH4+ NO3- [ Will always be soluble in water. Tells you what won’t precipitate, so assume the other one will
Examples • CaCO3 + 2 HCl → • Pb(NO3)2 + KI → • NaOH + KI → → CaCl2 + H2CO3 H2O + CO2 PbI2 + 2 KNO3 no reaction because both products are soluble NaI + KOH
Combustion • An element or compound reacts with oxygen • Usually produces heat → Exothermic • Combustion of a hydrocarbon always produces carbon dioxide and water • 2 Mg + O2 → • 2 CH3OH + 3 O2 → 2 MgO + heat 2 CO2 + 4 H20 + heat
Writing Molecular, Complete Ionic, and Net Ionic Equations • Molecular Equations: an equation showing the complete neutral formulas for every compound in the reaction. • AgNO3 (aq) + NaCl (aq)→ AgCl(s) + NaNO3 (aq)
Complete Ionic Equations: equations that show reactants and products as they are actually present in solution. • Ionic compounds dissociate (dissolve) in water, so they are written as individual ions…if the compound is soluble…check your solubility rules • Complete Ionic Equation of : • AgNO3 (aq) + NaCl (aq)→ AgCl(s) + NaNO3 (aq)
Spectator Ions: ions in solution that appear unchanged on both sides of the equation • Net Ionic Equation: equations which show only the species that actually participate in the reaction • Spectator ions are omitted from the net ionic equation
Write the Net Ionic Equation for:Ag+ (aq) + NO3- (aq) + Na+ (aq) + Cl- (aq) → AgCl(s) + Na+ (aq) + NO3-(aq)
Write the molecular, complete ionic and net ionic equations for the following: lead (II) nitrate reacts with lithium chloride.
Write the molecular, complete ionic and net ionic equations for the following:Hydrobromic acid reacts with calcium hydroxide