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ORGANIC CHEMISTRY. Organic Chemistry. Chemistry of carbon compounds Are called hydrocarbons Carbon can make four bonds that are very strong Chemical Formula – notation using symbols and numbers to represent the composition of a substance
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Organic Chemistry • Chemistry of carbon compounds • Are called hydrocarbons • Carbon can make four bonds that are very strong • Chemical Formula – notation using symbols and numbers to represent the composition of a substance • Structural Formula- shows the arrangement of atoms in a molecule
ALKANE SERIES • Saturated Hydrocarbons • Follow the formula CnH2n+2 • These molecules ONLY have single bonds (SATURATED) • Suffix is -ANE
MEMORIZE THESE PREFIXES • METH- one carbon • ETH- two carbons • PROP- three carbons • BUT- four carbons • PENT- five carbons • HEX- six carbons • HEPT- seven carbons • OCT- eight carbons • NON- nine carbons • DEC- ten carbons
Write the chemical and structural formula for the following • METHANE • C1H4 • PROPANE • C3H8 • PENTANE • C5H12
NAMING BRANCHED ALKANES • Find the longest chain of carbons • Parent chain • Number the carbons in the parent chain starting at the end closest to the first branch • This branch is designated with a number and has the suffix –yl • If more than one of the same kind of branch is found, use a prefix (di, tri) • If more than one kind of branch is found, list them in alphabetical order
Draw the structural formula for the following • 2-methylpentane • 2,2-dimethylhexane • 2,4-dimethylhexane • 3-ethyl-2,5-dimethylheptane
ISOMERS • A substance that has the same chemical formula as another substance but differs in structure • Draw and name the FIVE isomers of hexane
ALKENE SERIES • Unsaturated hydrocarbons • Have double bonds between carbon atoms • Follow the formula CnH2n
NAMING ALKENES • Alkenes are numbered starting at the side nearest the first double bond • The parent compound is named from the longest continuous chain containing the double bond • The suffix –ENE is used
3-hexene • 2-methylpropene • 4-propyl-4-octene
ALKYNES • Unsaturated hydrocarbons • Have TRIPLE bonds between carbon atoms • Follow the formula CnH2n - 2 • Use the suffix -YNE
CYCLIC HYDROCARBONS • Cycloalkanes • CnH2n • cyclohexane • ethylcyclohexane • 1,3-dimethylcyclohexane
Halogen derivatives • 2-bromopropane • 1,4-dichloro-1-butene • 1,3-dichlorobenzene
ORGANIC OXYGEN COMPOUNDS • R- represents any hydrogen radical • Alcohol: • Contain the hydroxyl group • R-O-H • Ending –ol • CH3OH – methanol • Ethanol • 2-propanol
Ethers • R – O – R • -oxy- • CH3OCH2CH3 methoxyethane • Propoxypentane
Aldehydes • R – C – H ll O • -al • CH3CH2CHO propanal • Pentanal
Ketones • R – C – R ll O • -one • CH3COCH2CH32-butanone • propanone (acetone) • pentanone
Organic Acids • R – C – O – H ll O • -oic acid • CH3CH2CH2COOH butanoic acid • pentanoic acid
Esters • R – C – O – R ll O • -yl oate • CH3CH2CH2OOCCH3 • propyl ethanoate • Ethyl pentanoate