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Trash Talk. Municipal Wastes Hazardous Wastes Toxicology. What is Municipal Waste. Sources Is there a waste cycle? Or is it better described as a waste stream? What do we discard? How much do we discard? What are the trends in waste production?. Municipal Waste . Non Hazardous Waste
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Trash Talk Municipal Wastes Hazardous Wastes Toxicology
What is Municipal Waste • Sources • Is there a waste cycle? • Or is it better described as a waste stream? • What do we discard? • How much do we discard? • What are the trends in waste production?
Municipal Waste • Non Hazardous Waste • Biodegradable vs. Non-biodegradable • Recyclable vs. non-recyclable • Combustible vs. non-combustible • Hazardous Waste • Problems • Lehigh County: Household Hazardous Waste Pickup
The total amount of solid waste disposal in the United States is increasing more slowly - landfill disposal is decreasing and recycling is increasing.
Disposal Methods • Open Dumps • Ocean Dumping • “Sanitary” landfills • Incineration • Trash to steam - energy recovery • NIMBY • Exporting waste
The Three R’s • Reducing • Reusing • Recycling
Reducing Waste Amounts • Packaging - 50% of domestic trash volume • Biodegradable plastics
Reusing • Returnable bottles-15 round trips • Glass beverage bottles - No longer use returnable, reusable glass bottles – Why? • “Bottle Bills” - but not PA!! • Examples of reusable items • What do you and your family reuse? • Why don’t you reuse more items?
Reusing • Contrast reuse and recycle • What are advantages of reusing? • Why does reusing save energy? Discuss at least one in detail.
Recycling • Dropoff vs. curbside pickup • Advantages - saves resources, energy • Japan’s recycling program • Economics- costs vs. benefits • Creating markets for recycled products • Composting
Recycling • Contrast postconsumer and preconsumer recycling • 30% of U.S. MSW recycled • What are key products recycling? • What can be composted? • What is a materials-recovery facility? • Contrast source separation with mixed urbane waste. • Advantages and disadvantages
Aluminum can, used once Steel can used once Recycled steel can Glass drink bottle used once Recycled aluminum can Recycled glass drink bottle Refillable drink bottle, used 10 times 0 8 16 24 32 Energy (thousands of kilocalories)
Why not more recycling • Discuss the following – what is your opinion and why? • Markets • Tax breaks and subsidies • Requiring government purchase (even if more expensive) • Making companies responsible for all the wastes they produce
Laws requiring a deposit for beverage containers • “Bottle Bills” – laws that require deposit for beverage container • Many states – NY, Vermont, Cal, and more • but not PA!!
What about E-Waste • What are the issues? Why is this a special problem?
Hazardous Wastes • Flammable or explosive • Corrosive or reactive • Toxic-carcinogenic, mutagenic,teratogenic • Infectious • Radioactive
Hazardous and Toxic Waste • More than one ton per person of officially classified hazardous waste • Biggest sources: chemical and petroleum • 60 million tons does not enter waste stream
Toxic Chemicals - Classification • Irritants-corrosives; acids,metal fumes, chlorine, formaldehyde • Asphyxiants-prevent or interfere with oxygen uptake; carbon monoxide and hydrogen cyanids • Allergens-formaldehyde; PCBs, • Neurotoxins-lead & mercury; chlorinated hydrocarbons (DDT, Aldrin) organophosphates (malathion) • Mutagens-damage DNA; cancer;inheritance • Teratogens-thalidomide • Carcinogens
Toxicity Measurement • Animal Testing • Dose-response assessment- “the dose makes the poison” • Toxicity levels • Exposure assessment - LD50 • Detectable levels - becoming much more sensitive • Variation of sensitivities within a population
Specific Toxics and Threats (547 to 552) • Lead • Mercury • Chlorine • Dioxins
Legacy • 5 billion metric tons improperly disposed of between 1950-75 • Dump sites, midnight dumping, railroad yards (and ocean and bay dumping) • 36,000 “seriously contaminated sites” • 1400 on National Priorities List; very few cleaned up (about 100) • Superfund
Legacy of Toxic Waste Disposal • Landfills, warehouses, wells, oceans, waterways, burning, “midnight dumping”, and railroad yards Equals • A toxic nightmare (thanks to our predecessors) • So, along comes CERCLA, the Superfund Act of 1980, and amended, and reauthorized • Originally only 1.6 billion dollars
Superfund • What is the purpose of Superfund? • Who is liable? • 1400 sites on the National Priority List • And as many as 36,000 seriously contaminated sites :-( • How does one get the distinction of an NPL listee? • By 1997: $38 billion, but only 100 sites remediated----WHY?
CERCLA – 1980Comprehensive Environmental Response, Compensation and Liability Act • The “Superfund Act” • Discuss 4 goals of the act • “Polluter-pays principle” • Positive and negative impact of this “liability” • National Priorities List – 1900 sites • 750 cleaned up • Examples – Pennsylvania Sites • In Emmaus – Rodale Manufacturing Site • Palmerton Zinc Site • Images of Palmerton Zinc
Where are the Sites? • Love Canal • Along Great Lakes and Gulf Coast • Industrialized areas of Northeast
RCRA – 1976Resource Conservation and Recovery Act • Cradle-to-grave system • Discuss this • Purpose of law
What is a Brownfield? • Potential or actual contaminated sites • Would you purchase or develop them? • Liability • Degree of purity required • Efforts to encourage development of brownfield areas
What to do with Toxic Waste? • Reduce or eliminate - alter manufacturing processes • Surplus material exchange • Treatments-physical (separation from water) • Chemical processing • Incineration • Bioremediation (genetic engineering!) • Secure landfills • Permanent retrievable storage