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M. Schwikowski 1 , H.W. Gäggeler 1,2 , U. Schotterer 2 1 Paul Scherrer Institute, Switzerland

A 500 year palaeo record of sulphate and m ineral d ust from an A lpine ice core (Colle Gnifetti, Swiss Alps ). M. Schwikowski 1 , H.W. Gäggeler 1,2 , U. Schotterer 2 1 Paul Scherrer Institute, Switzerland 2 Department of Chemistry and Biochemistry, University of Berne, Switzerland.

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M. Schwikowski 1 , H.W. Gäggeler 1,2 , U. Schotterer 2 1 Paul Scherrer Institute, Switzerland

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  1. A 500 year palaeo record of sulphate and mineral dust from an Alpine ice core (Colle Gnifetti, Swiss Alps) M. Schwikowski1, H.W. Gäggeler 1,2, U. Schotterer2 1 Paul Scherrer Institute, Switzerland 2 Department of Chemistry and Biochemistry, University of Berne, Switzerland

  2. Motivation • Reconstruction of local and regional climate and atmospheric parameters • Documentation of the effects of anthropogenic emissions

  3. The ice core • Drilling site: Colle Gnifetti glacier saddle at 4450 m asl in the Monte Rosa area • Length: 124 m (bedrock) • Accumulation rate: 0.3 m water equiv. y-1 • Cold glacier: firn temperatures << 0°C

  4. Location

  5. Time period accessible by this ice core Dating error: ± 2 years Dating error: ± 20 years

  6. Mineral dust tracer Ca2+1977 Saharan dust event

  7. Mineral dust recordExtrem events: Saharan dust 2529 samples (5 per year) 1937 1901 1977

  8. Mineral dust record: long term trendIncreased Ca2+ from1450 to 1620 (LIA?) 5-year averages Little Ice Age in NH: cold, dry, increased atmospheric circulation

  9. Sea salt record (Strength of Westerlies) No trend 5-year averages

  10. nssSulphate recordAnthropogenic emissions, Saharan dust

  11. nssSulphate trendincreased concentrations from 1870-1970 5-year averages

  12. Trend in nssSO42-/Ca2+ ratioChange in mineral dust source or SO2 emissions?

  13. Source contribution to SO42- (eq L-1)

  14. Oldest ice

  15. Conclusion • No change in frequency of major Saharan dust transports • From 1450 to 1620 A.D. increased input of mineral dust and lower nssSO42-/Ca2+ ratios (probably related to LIA) • No change in strength of Westerlies • Change in area of mineral dust source (and probably in pre-industrial SO2 emissions)

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