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1. 1 Composition of the Earth GLY 4200
Fall, 2011
2. 2 Interior of the Earth Earths interior is divided into zones, with differing properties and compositions
Since we live on the crust, it is the most studied
The core and mantle are very important in understanding the behavior of the earth Diagram: earthint.gofDiagram: earthint.gof
3. 3 Composition of the Crust Major Elements Earths crust is composed predominantly of eight elements
Figure for Si here is correct figure 5.2 in text has a misprint
Numbers are in weight percent
4. 4 Abundances Measurements We can specify abundances using differ methods
The most common are:
Weight per cent
Atom per cent
Volume percent
5. 5 Comparison of Methods
6. 6 Minor and Trace Element Definition Minor elements have abundances between 0.1 to 1.0 weight percent
Elements with abundances less than 0.1% are called trace elements
Their abundance is usually given in parts per million (ppm) or parts per billion (ppb)
7. 7 Minor and Trace Elements in Crust Only 17 elements occur with abundances of at least 200 parts per million (ppm) in addition to those on the major element slide, these include:
8. 8 Ores Many valuable elements are in the trace element range, including the gold group (Au, Ag, and Cu) and the platinum group (Pt, Pd, Ir, Os), mercury, lead, and others
Useage does not always reflect abundance copper (55 ppm) is used more than zirconium (165 ppm) or cerium (60 ppm)
9. 9 Effect of Pressure As pressure increases, minerals transform to denser structures, with atoms packed more closely together
This is seen in the mantle
The upper mantle is dominated by the mineral olivine, Mg2SiO4
Magnesium is in VI, and Si in IV
10. 10 Transition Zone In the transition zone, from about 400 to 660 kilometers below the surface, olivine transforms to denser structures
olivine (? = 3.22 gm/cm3) ? wadsleyite (? = 3.47 gm/cm3) ? ringwoodite (? = 3.55 gm/cm3)
11. 11 Lower Mantle Pressures are so great that silicon becomes six coordinated (CN = VI), and some magnesium becomes eight-coordinated (perovskite structure)
Ringwoodite (? = 3.55 gm/cm3) ? MgSiO3 (perovskite structure) and (Mg, Fe)O (magnesiowustite - halite structure)
12. 12 Core The core is divided into two regions, the liquid outer core and the solid inner core
There is a definite chemical discontinuity between the lower mantle and the outer core
The main elements in the core are an iron and nickel alloy
Increasing temperature first melts the alloy to make the outer core
Increasing pressure freezes the alloy to produce the inner core
13. 13 Outer Core Ranges from 2900 to 5100 kilometers below the earth
Composition is iron with about 2% nickel
Density of 9.9 gm/cm3 is too low to be pure metal
Best estimates are that silica makes up 9-12% of the outer core
14. 14 Inner Core From 5100 to 6371 kilometers below surface
80% iron, 20% nickel alloy
Pressures reach about 3 megabars, or 300,000 megapascals
Temperature at the center is about 7600C