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Quaestio : How do organisms obtain the energy stored in food?. Nunc Agenda: List what foods you have eaten today and the types of molecules that compose them. Energy. Energy : the ability to do work. Can you think of examples? In what forms does energy exist ?
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Quaestio: How do organisms obtain the energy stored in food? Nunc Agenda: List what foods you have eaten today and the types of molecules that compose them.
Energy • Energy: the ability to do work. • Can you think of examples? • In what forms does energy exist? • How do we use energy on earth?
A cell does 3 main kinds of work: • Mechanical work: beating cilia, contraction of muscle cells, movement of chromosomes during reproduction • Transport work: moving substances across membranes • Chemical work: running chemical reactions, synthesis of polymers from monomers
The Law of Conservation of Energy • The Law of Conservation of Energy: Energy can neither be created nor destroyed; it can only change forms. • Remember, the sum of energy in the universe is constant. • Examples of energy conversions: • Photosynthesis • (Light E Electrical E Chemical E) • Respiration • (Chemical E Kinetic E Thermal E) • Internal Combustion Engine • (Chemical E Thermal E Kinetic E).
Energy for Living Things • All living things need energy to carry out their life processes. • Nutrition: the life process in which organisms obtain energy in food for metabolic processes. • Energy must exist to run “cellular machinery.”
Examples of Energy Needs • 1. Locomotion. (Muscle Contractions) • 2. Building complex molecules from simple ones (Synthesis). • 3. Digestion. • 4. Breathing, Talking, Thinking, Existing!
A Heterotroph’s nutrition must supply the organism with enough chemical energy to fuel its life’s activities. Heat CO2 + Chemical energy H2O
In fireflys, Energy in the form of ATP combines with an enzyme to run a chemical reaction to produce flashes of lights
Ctenophores (Comb Jellies),like fireflies, have bioluminescence using the power of ATP.
Energy from Food • Living things rely on the chemical energy stored in their food to survive. • Carbohydrates, lipids, and proteins all have chemical energy and all can be broken down to yield energy • known as cellular respiration • Carbohydrates are the foods most commonly broken down. • Created during photosynthesis
ATP and ADP • Cells use chemical energy in the form of ATP • The energy released during cellular respiration is “stored” in the form of ADP and ATP. • ADP: Adenosine diphosphate • Has two phosphate groups. • ATP: Adenosine triphosphate • Has three phosphate groups
Behind the Names • Adenosine is the combination of a molecule of the nitrogenous base adenine with a molecule of the sugar ribose. • Adenine + Ribose = Adenosine • Diphosphate = 2 phosphate groups attached to adenosine. • Triphosphate = 3 phosphate groups attached to adenosine.
ATP: C10H16N5O13P3 : Nitrogenous Base : 5-carbon sugar
Molecular Similarities • ATP and ADP use the same subunits as the nucleic acids: • A nitrogenous base (adenine is present in DNA and RNA). • A 5-carbon sugar (ribose is present in RNA only). • Can you remember what DNA has? • Phosphate groups
What makes ADP and ATP so important? • ATP has more energy than ADP: • due to a high-energy bond between the 2nd and 3rd phosphate group • When the third phosphate group is removed from ATP, it forms ADP, and chemical energy is released. • ATP + H2O ADP + P + Energy
Phosphorylation • Phosphorylation: the transfer of energy when a phosphate group is transferred among molecules. • Phosphorylation is a common way for chemical energy to be transferred in living cells. • ATP loses a phosphate to the molecule that becomes phosphyorylated.
ATP is recycled • ATP is used continuously by a cell, but it can be regenerated by adding a phosphate to ADP. • It’s a renewable resource! • If ATP could not be regenerated by the phosphorylation of ADP, humans would consume nearly their body weight in ATP each day
AMP • AMP stands for adenosine monophosphate. It has only one phosphate group attached. • AMP has lower energy than ADP (and ATP). • ADP is rarely broken down into AMP for energy.
The Role of Glucose. • Glucose (a simple sugar) is broken down to supply the energy needed to add a phosphate group to ADP to form ATP. • One C6H12O6 molecule can be used to form 36 molecules of ATP.
More on Carbohydrates • Glucose is not usually present in its simple form in the foods we eat. • We need to break complex carbohydrates into glucose first. • Review: Our digestive system breaks down complex carbohydrates: • Starch Maltose Glucose • Can you remember what enzymes are involved and where?
Question • If ATP is directly used for energy, why do we need glucose at all? Answer: Glucose contains a lot more energy than ATP, but is actually a smaller molecule. Glucose is a good way to store chemical energy, while ATP is more appropriate for directly supplying immediate energy for cellular reactions.
More on ATP vs. Glucose • Glucose Chemical Formula • C6H12O6 • Smaller Molecule with More Energy. • ATP Chemical Formula • C10H16N5O13P3 • Larger Molecule with Less Energy.
Glucose holds more energy than ATP Glucose ATP
Glucose vs. ATP • Like a gold bar • Cash! Can you explain the analogy? Glucose is smaller but holds more energy, and needs to be broken down or exchanged before you can purchase with it. A suitcase full of money may be larger, like ATP, but can be used immediately.
Questions • If ATP is used as the main source of energy in a cell, then why does a cell only keep a small amount of ATP present at any time? • ATP is constantly being recycled from ADP
Ways to transfer energy in the cell • Transfer phosphate groups • Transfer electrons • Transfer hydrogen
Oxidation-Reduction Reactions: the transfer of electrons • Oxidation: A chemical change in which an atom or a molecule loses electrons. • Example: When sodium combines with chlorine to form sodium chloride (NaCl), sodium loses an electron to become a sodium ion (Na+). • Reduction: A chemical change in which an atom or a molecule gains electrons. • Example: Chlorine gains the electron from sodium, becoming a chloride ion (Cl-).
Questions • Why did sodium (Na) become Na+? • Why did chlorine (Cl) become Cl-? Answer: Sodium lost an electron and became a positive ion. It now has more protons than electrons. Sodium was oxidized. Answer: Chlorine gained an electron and became a negative ion. It now has more electrons than protons. Chlorine was reduced.
Remember Oil Rig! Oxidation Is Loss (of electrons) Reduction Is Gain (of electrons)
Another way to remember:LEO goes GER • Lose • Electrons • Oxidation • Gain • Electrons • Reduction
Oxidation-Reduction Reactions • When one substance is oxidized, another must be reduced. • Redox Reaction: (short for Reduction-Oxidation Reaction): A reaction that involves both oxidation and reduction.
Gaining and Losing Hydrogen • Occasionally, rather than exchanging electrons, molecules will exchange hydrogen atoms. • Recall: a hydrogen atom consists of one proton and one electron. It is the simplest element. • The molecule that loses the hydrogen is oxidized • called the oxidant. • The molecule that gains the hydrogen is reduced • called the reductant.
Hydrogen Ion = H+ = Proton Hydrogen was Oxidized
Redox Reactions, Cont’d • Redox reactions involve a transfer of energy. • The oxidant (the electron or hydrogen donor) normally loses energy and the reductant (the electron or hydrogen acceptor) gains energy.