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2. C-H activation: Process where a strong C-H bond undergoes substitution to produce a weaker C-M bond.Functionalisation: Metal-C bond is replaced by any bond except C-H.The challenge: Finding ways to selectively form the C-M intermediate under synthetically useful, mild conditions that enable functionalisation and catalyst renewal..
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4. 4 18 Electron Rule
5. 5 Direct Borylation of Alkanes: Initial Work
6. 6 Direct Borylation of Alkanes: Initial Work
Proposed Mechanism
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9. 9 Direct Borylation of Alkanes: Thermal
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14. 14 Proposed high-valent Rh(V) and Ir(V) boryl complexes as intermediates in these reactions
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26. 26 Direct Arene Borylation : Suzuki Precursors
27. 27 Direct Arene Borylation : One Pot Oxidation
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