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Kwart, H.; Khan, A. A. J. Am. Chem. Soc. 1967, 89 , 1951–1953. Breslow, R.; Gellman, S. H. J. Chem. Soc., Chem. Com

Kwart, H.; Khan, A. A. J. Am. Chem. Soc. 1967, 89 , 1951–1953. Breslow, R.; Gellman, S. H. J. Chem. Soc., Chem. Comm. 1982, 1400–1401. Breslow, R.; Gellman, S. H. J. Am. Chem. Soc. 1983 , 105, 6728–6729. Müller, P. et al. Tetrahedron 1996 , 52 , 1543–1548.

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Kwart, H.; Khan, A. A. J. Am. Chem. Soc. 1967, 89 , 1951–1953. Breslow, R.; Gellman, S. H. J. Chem. Soc., Chem. Com

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  1. Kwart, H.; Khan, A. A. J. Am. Chem. Soc. 1967,89, 1951–1953. Breslow, R.; Gellman, S. H. J. Chem. Soc., Chem. Comm. 1982, 1400–1401.

  2. Breslow, R.; Gellman, S. H. J. Am. Chem. Soc.1983, 105, 6728–6729.

  3. Müller, P. et al. Tetrahedron 1996, 52, 1543–1548. Müller, P. et al. Helv. Chim. Acta 1997, 80, 1087–1105.

  4. Müller, P. et al. Helv. Chim. Acta 1997, 80, 1087–1105.

  5. Müller, P. et al. Helv. Chim. Acta 1997, 80, 1087–1105.

  6. Du Bois, J. et al. Angew. Chem. Int. Ed.2001, 40, 598–600.

  7. Du Bois, J. et al. Angew. Chem. Int. Ed.2001, 40, 598–600.

  8. Du Bois, J. et al. Angew. Chem. Int. Ed.2001, 40, 598–600.

  9. Du Bois, J. et al. J. Am. Chem. Soc.2001, 123, 6935–6936.

  10. Du Bois, J. et al. Org. Lett. 2003, 5, 4823–4826.

  11. Du Bois, J. et al. Org. Lett. 2003, 5, 4823–4826.

  12. Du Bois, J. et al. J. Am. Chem. Soc.2004, 126, 15378–15379.

  13. Du Bois, J. et al. Org. Lett. 2006, 8, 1073–1076.

  14. Lebel, H. et al. J. Am. Chem. Soc. 2005, 127, 14198–14199.

  15. Müller, P. et al. Helv. Chim. Acta 2004, 87, 1607–1615.

  16. Davies, H. M. L. Org. Lett. 2006, 8, 5013–5016.

  17. Hashimoto, S. et al. Tetrahedron Lett. 2002, 43, 9561–9564.

  18. Müller, P. et al. Angew. Chem. Int. Ed. 2006, 45, 4641–4644.

  19. Müller, P. et al. Angew. Chem. Int. Ed. 2006, 45, 4641–4644.

  20. Davies, H. M. L. et al. Org. Lett. 2006, 8, 5013–5016.

  21. Du Bois, J. et al. J. Am. Chem. Soc.2004, 126, 15378–15379.

  22. General reactivity trend: 3° > α-ethereal ≥ benzylic > 2° >> 1° Du Bois, J. et al. J. Am. Chem. Soc. 2007, 129, 562-568.

  23. Du Bois, J. et al. J. Am. Chem. Soc. 2007, 129, 562-568.

  24. Du Bois, J. et al. J. Am. Chem. Soc. 2007, 129, 562-568.

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  26. Du Bois, J. et al. J. Am. Chem. Soc. 2007, 129, 562-568.

  27. Du Bois, J. et al. J. Am. Chem. Soc. 2007, 129, 562-568.

  28. Du Bois, J. et al. J. Am. Chem. Soc. 2007, 129, 562-568.

  29. Du Bois, J. et al. J. Am. Chem. Soc.2001, 123, 6935–6936.

  30. Du Bois, J. et al. J. Am. Chem. Soc. 2002, 124, 12950–12951.

  31. Du Bois, J. et al. J. Am. Chem. Soc. 2003, 125, 2028–2029.

  32. Du Bois, J. et. al. J. Am. Chem. Soc. 2006, 128, 3926–3927.

  33. Du Bois, J. et al. J. Am. Chem. Soc. 2003, 125, 11510–11511.

  34. Du Bois, J. et al. Org. Lett. 2006, 8, 1073–1076.

  35. Professor Tehshik Yoon Dr. Timothy Clark Dr. Hairong Guan Eun Jin Cho Michelle Rogers Kim Peterson Chris Scarborough Margaret Wong April Benkovics Yoon group members: Charles Allen David Michaelis Katie Partridge Chris Shaffer Mary Beth Anzovino Michael Ischay Alex Khrizman

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