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Warm Up 10/19/12. How long have people been interested in understanding matter and its structure? Thousands of years Hundreds of years A few years Never. History of Atomic Structure. What is an atom?. The smallest particle of an element.
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Warm Up10/19/12 How long have people been interested in understanding matter and its structure? • Thousands of years • Hundreds of years • A few years • Never
What is an atom? • The smallest particle of an element. • Atoms are so small that we cannot even see them with a microscope. • How do scientists know what they look like or how they are made?
Democritus Aristotle http://www.youtube.com/watch?v=lY-Thmrt1Ts
Ancient Philosophy • Who:Aristotle, Democritus • When:More than 2000 years ago • Where:Greece • What: • Aristotlebelieved in 4 elements: Earth, Air, Fire, and Water. • Democritusbelieved that matter was made of small particles that could not be divided. He named them “atoms” meaning uncut or indivisible. • Why:Aristotle and Democritus used observation and inference to explain the existence of everything.
Alchemists • Who:European Scientists • When:800 – 900 years ago • Where:Europe • What:Their work developed into what is now modern chemistry. • Why:Trying to change ordinary materials into gold.
Becquerel and Curie • Henri Becquerel—(1896)-- While studying the effect of x-rays on photographic film, he discovered some chemicals spontaneously decompose and give off very penetrating rays. • Marie Curie—(1898)--Studied uranium and thorium and called their spontaneous decay process "radioactivity". She and her husband Pierre also discovered the radioactive elements polonium and radium.
Lavoisier— elements combine to form compounds. • Proust—Law of Definite Proportions • The mass of elements of reactants equals the mass of elements of products.
Particle Theory • Who:John Dalton • When:1808 • Where:England • What: Described atoms as tiny particles that could not be divided. Thought each element was made of its own kind of atom. • Why:Building on the ideas of Democritus in ancient Greece.
John DaltonThe Atomic Theory • All elements are composed of atoms. • All atoms of the same element are the same, but different from other elements. They have same size, mass and properties. • Compounds contain atoms of more than one element, combined in whole number ratios. • Compounds form when atoms join, separate, or rearrange.
Discovery of Electrons • Who:J. J. Thompson • When:1897 • Where:England • What:Thompson discovered that electrons were smaller particles of an atom and were negatively charged. • Why:Thompson knew atoms were neutrally charged, but couldn’t find the positive particle.
J. J. Thomson • First to show atoms are made of subatomic particles. • Plum pudding model or chocolate chip ice cream model. Pudding or ice cream is positive charged mass o f matter and plums or chocolate chips are the negative charges evenly scattered throughout the atom. • Used an electric current and the cathode ray tube to learn more about atoms.
Atomic Structure I • Who:Ernest Rutherford • When:1911 • Where:England • What:Conducted an experiment to isolate the positive particles in an atom. Decided that the atoms were mostly empty space, but had a dense central core. • Why:He knew that atoms had positive and negative particles, but could not decide how they were arranged.
Rutherford • The atom is mostly empty space. • All of the positive charge is located in the center of the atom in the nucleus. • Electrons move randomly in the space around the nucleus. • Used the gold foil experiment. • http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/ruther14.swf
Chadwick • Protons and neutrons in nucleus. • Protons –positive • Neutrons-neutral • Electrons-negative • Proton mass = neutron mass; electrons much smaller
Atomic Structure II • Who:Niels Bohr • When:1913 • Where:England • What:Proposed that electrons traveled in fixed paths around the nucleus. Scientists still use the Bohr model to show the number of electrons in each orbit around the nucleus. (energy levels) • Why:Bohr was trying to show why the negative electrons were not sucked into the nucleus of the atom.
Modern Model/Wave ModelShrodinger—Electron Cloud Model • Uses mathematical model to describe the certainty of finding an electron at a certain location on the electron cloud. • The electron cloud is a visual model of the most likely locations for the electrons. Where the cloud is denser, there is more probability of finding an electron. • An electron can move from one energy level to another when the atom gains or loses energy.
Electron Cloud Model • Electrons travel around the nucleus in random orbits. • Scientists cannot predict where they will be at any given moment. • Electrons travel so fast, they appear to form a “cloud” around the nucleus.
http://www.youtube.com/watch?v=wJ2e-uPmdYg • Atomic Theory Song: http://www.youtube.com/watch?v=vUzTQWn-wfE
Atomic Orbitals • An orbital is a region of space around the nucleus where an electron is likely to be found. • An electron cloud is a good approximation of how electrons behave in their orbitals. • Each orbital can contain 2 electrons.
Isotopes • Isotopes can be shown in several ways. • Symbol-Atomic Mass • H-1 (P=__, E=__, N=__) • H-2 (P=__, E=__, N=__) • H-3 (P=__, E=__, N=__) • It can also be shown:
History of the Periodic Table • Mendeleev- Father of the Periodic Table; Arranged table according to increasing mass. • Moseley- Improved the table by arranging it according to atomic number (number of protons). There are a few places on the chart where the mass decreases. • Seaborg-pulled out the f block.
Arrangement of the Periodic Table • Elements are arranged by atomic number (number of protons). • Each row on the periodic table is a period. • Each column on the periodic table is a group. • Similar electron configurations. • Similar chemical properties.
Classes of Elements • There are many different ways to classify elements. • State of matter • Solids—black symbol • Liquid—blue symbol • Gas—red symbol • Occurrence in nature • Elements that do not occur naturally—white symbol • General properties • Metal • Nonmetal • Metalloid
Metals • The majority of the elements on the periodic table. • Solids (except Hg) • Good conductors of heat and electricity • Malleable- can be hammered into sheets • Ductile- can be drawn into wires • Have luster (shiny) • Found to the left of the stairstep.
Transition Metals • Metals in groups 3-12. • Form a bridge between the elements on the left and right sides of the table. • Among the first discovered (Au, Ag, Cu) • They form compounds with distinctive colors.
Nonmetals • Generally have properties opposite of metals. • Poor conductors of heat and electricity. • Nonmetals have low boiling points—many nonmetals are gases at room temperature. • Brittle solids (will shatter if hit with a hammer) or gases (b/c low boiling points)
Metalloid • Located between metals and nonmetals---touch the stairstep. • Have some properties of metals and some of nonmetals. • A metalloid’s ability to conduct electric current varies with temperature. • Si and Ge are good insulators at low temperatures, but good conductors at high temperatures. • Semiconductors—used in computer chips.
As you move across the period, from left to right, the elements become less metallic and more nonmetallic in their properties. • Elements in a group have similar properties because they have the same number of valence electrons. They won’t be identical because they have different number of energy levels.
Families • Alkali Metals • Alkaline Earth Metals • Transition Metals • Boron Group • Carbon Group • Nitrogen Group • Oxygen Group • Halogens • Noble Gases
Alkali Metals • They have one outer (valence) electrons so they are very reactive. • They are only found as compounds in nature—because they are so reactive. • Reactivity increases as you move down the group. • Ex. Sodium • Stored under oil b/c so reactive • Makes NaCl • Video or Na reactivity
Alkaline Earth Metals • Have 2 valence electrons. • Mg, Ca, Be
The Boron and Carbon Families • Boron • Aluminum is the most abundant metal in the Earth’s crust. • Bauxite is made from Al and O. • Carbon Group • Except for water, most of the compounds in your body contain carbon. • Si is second most abundant element in Earth’s crust.
Nitrogen group—N and P in fertilizer • Oxygen group—O most abundant element in Earth’s crust. • Halogens—They all have similar chemical properties.. Very, very reactive. • Noble gases- colorless, odorless, and extremely unreactive.