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UNIT 1 (Chapter 2) Units of Measurement. Accuracy- How close you are to the mark you are trying to hit Closeness of measurements to the correct or accepted value of the quantity measured. Precision- How close the measurements are to each other.
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Accuracy- • How close you are to the mark you are trying to hit • Closeness of measurements to the correct or accepted value of the quantity measured. • Precision- • How close the measurements are to each other. • Closeness of a set of measurements of the same quantity made in the same way. Accuracy and Precision (dart board example)
Three students were each asked to prepare 5 samples of sodium chloride crystals that weigh ~10.0 g each. After preparing the samples, each sample was weighed and the following measurements were recorded. Which set of measurements are the most accurate? The least accurate? Which set of measurements are the most precise? The least precise?
Using a ruler, measure a small object in centimeters (pen, pencil, book thickness, etc.) Record your measurement. How certain are you that _____________is ______________ long? Is it exactly _____________ long or is it a little more or a little less? Measurement Activity
Report measurements to one decimal place past the smallest graduation on the instrument. If you say someone is 6.0000 feet tall, you are saying that the instrument you are using to measure height can accurately measure to the thousandths place! Rule for measurement
Rules (from p.47 in the textbook) • Zeros appearing between nonzero digits are significant. • Zeros appearing in front of all nonzero digits are not significant. • Zeros at the end of a number and to the right of a decimal point are significant. • Zeros at the end of a number but to the left of a decimal point may or may not be significant. Zeros as placeholders are not significant. Use a decimal after the zeros if the zeros are considered significant. Significant Figures
35.2 m 10.04 g 0.00020 kg 2000 lb 2000. lb 1.25000 m3 How many Significant Figures are in each of these measurements? (work in groups)
Rules for Rounding- do not follow rules given in Table 6 (too complicated!) • Rules for Addition/ Subtraction with Decimals • Answer must have same number of digits to the right of the decimal place as there are in the measurement having the fewest digits to the right of the decimal point • Rules for Multiplication/ Division • Answer can have no more significant figures than are in the measurement with the fewest number of significant figures Significant Figures (p.48-49)
5.44m – 2.6103m = • 2.83m (2 decimal places) • 2.4 g/ml x 15.82 ml = • 38g (2 sig figs) Examples
Complete Measurements and Calculations: Significant Figures Worksheets D and E (standard chemistry) Complete 3-page packet (honors chemistry)
Always put the decimal after the 1st number and using the 4th number, round back to the 3rd number for 3 significant figures. 1400 = 1.40 x 103 .00001256 = 1.26 10-5 Scientific Notation & Significant Figures
SI (Le Système International d’Unités)/ Metric System • World’s most widely used system of measurement • 7 base units (length, mass, time, temperature, amount of substance, electric current, luminous intensity- see p.34) • U.S. Customary System (developed from English system) • We need to be able to convert units within each system and between the two systems. Units of Measure
Conversion factors- • Ratios derived from the equality between two different units that can be used to convert from one unit to the other • See Metric Prefixes and Conversion Factors handout • 1 ft = 12 in. • Write this as 1 ft or 12 in 12 in 1 ft Convert 78.0 inches to feet. Convert 78.0 inches to centimeters. 6.5 feet or ~198 cm
One given: (examples to follow) First step is always to start with the given/1. Multiple givens: Try to find a given with no denominator if possible and start with that given/1 how do I start?
Each step should cancel out a previous unwanted unit and bring in other units that are progressing toward the desired units of the answer. 5 gallons of water weighs _________ kg? 5 gal 4qt 1L 1000ml 1g 1 kg ------ x ------ x ---------- x ---------- x ------ x ------- = 1 1 gal 1.06qt 1L 1ml 1000g How to go to 2nd, 3rd, etc. steps
The math of the previous problem is most easily handled as a “chain operation”. All numbers in the numerator are multipliers and all numbers in the denominators are divisors. Example from previous slide: 5 x 4 / 1.06 x 1000 / 1000 = 18.9 Calculator Use
Sample Problem • Express a mass of 5.712 grams in milligrams and in kilograms. • What are the possible conversion factors? • 5712 mg • 0.005712 kg
Conversion worksheets (standard) What Am I Eating? (honors) Class Work
Mass • Measure of the quantity/amount of matter • Does not depend on gravity • Weight • Measure of the gravitational pull on matter In space there is no gravity so you are weightless, but you still have the same mass as you do on earth. On other planets with different gravitational pull, you would weight more or less. Mass and Weight- what is the difference?
Density = Mass Volume D = m/ V Densities of common materials given on p.38 in Table 4. Density
A sample of aluminum metal has a mass of 8.4g. The volume of the sample is 3.1 cm3. Calculate the density of aluminum. What are we given? What are we trying to find? D = m/ V 8.4g = 2.7 g/cm3 3.1 cm3 Density Problem
Given the density and mass, find the volume. V = m/ D Given the density and volume, find the mass. m = D * V Variations on Density Problems
The volume of a copper wire is 1000 cm3. The density of copper is 8.92g/cm3. What is the mass of the copper wire? m = D * V 1000 cm3 * 8.92g/cm3 = 8920 cm3 Problem
Complete Measurements and Calculations: Density worksheet Class Work
Polycarbonate plastic has a density of 1.2 g/cm3. A photo frame is constructed from two 3.0 mm sheets of polycarbonate. Each sheet measures 28 cm by 22 cm. What is the mass of the photo frame? 1.2 g/cm3 x 3.0 m x 1 cm x 28 cm x 22 cm x 2 10 mm = 440 g Additional Example
Can be calculated for one experimental/measured data point or a set of data Compares the experimental value/set of values to the correct or accepted value (given or look up) % Error = Value experimental – Value accepted x 100% Value accepted When would percentage error be negative? Positive? Sample problem on p.45 Percentage Error
Complete Measurements and Calculations: Sample Problem C: Percentage Error worksheet Now we need to know how to write our answers using scientific notation and the correct number of significant figures. Homework
Worth its Weight in Gold Activity https://www.youtube.com/watch?feature=player_embedded&v=dJ920fat50M