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Dive into the world of organic chemistry, learning about hydrocarbons, alkyl groups, isomers, aromatics, and more. Explore fundamental concepts and naming conventions in this comprehensive guide.
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Organic Chemistry John Romano Zack Daniels Kate Neigish Jackie Laboe
Organic • Organic refers to compounds containing carbon, and often hydrogen, oxygen, and other non-metal elements • Three common characteristics: • Bonds are covalent (non-ionic) • Each carbon forms a total of four bonds • Carbon atoms can be bonded to each other or to other nonmetal atoms (hydrogen, halogens, oxygen, nitrogen, etc)
Hydrocarbons • Simplest type of organic compound consisting solely of hydrogen and carbon atoms
Alkanes • Saturated Hydrocarbons: single bonded carbon atom • Have the ending “-ANE” Ethane
Alkenes • Unsaturated Hydrocarbons: double bonded carbon atom • Have the ending “-ENE” Ethene
Alkynes • Unsaturated Hydrocarbon with a triple bonded carbon atom • Have the ending “-YNE” Ethyne
Alkyl Groups Chains that are added on to hydrocarbons and affect nomenclature, being preceded by numeric indication of their location Methyl: CH3--- Ethyl: CH3---CH2 Propyl: CH3--- CH2--- CH2
Branched Chains • When a hydrocarbon is not a straight-chain, the naming is more complex • The suffix indicates parent chain • The prefix indicates branching group the number indicates its location
Geometric Isomers • Same formula but different orientation • Cis same side of carbons • Trans different side of carbons Cis-2-Butene Trans-2-Butene
Joke Time…. • Name this compound:
Answer…. • ¡¡¡TRANSPARENT!!!
Aromatics • Derived from the single compound of Benzene, C6H6, which is in a hexagonal shape (three single / three double bonds). • Functional groups bonded to compound are named as a prefix to “-benzene” Chlorobenzene
Functional Group Orientation • Isomers of benzene have three prefixes for orientation of dual functional groups Para- Meta- Ortho- 1,4-dichlorobenzene 1,3-dichlorobenzene 1,2-dichlorobenzene