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Ozone good & bad. Ozone In the Atmosphere. 100. 60. Thermosphere. 80. 50. 40. Mesosphere. 60. Altitude (miles). 30. Altitude (km). 40. 90% of ozone is in the stratosphere. 20. 20. 10. 10% of ozone is in the troposphere. Troposphere. 0. 0. 0. 2. 4. 6. 8.
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Ozone In the Atmosphere 100 60 Thermosphere 80 50 40 Mesosphere 60 Altitude (miles) 30 Altitude (km) 40 90% of ozone is in the stratosphere 20 20 10 10% of ozone is in the troposphere Troposphere 0 0 0 2 4 6 8 Ozone (parts per million)
Ozone is the Earth’s natural sunscreen 100 60 Thermosphere 80 50 UVc - 100% Absorption Mesosphere UVb - 90% Absorption 40 UVa - 50% Absorption & Scattering 60 Altitude (miles) 30 Altitude (km) 40 20 20 10 Troposphere 0 0 0 2 4 6 8 Ozone (parts per million)
Chemicals that Destroy Stratospheric Ozone • Cl is much more abundant than Br • Br is about 50 times more effective at O3 destruction From Ozone FAQ - see http://www.unep.org/ozone/faq.shtml
October Average Ozone Hole Low Ozone High Ozone
Tropospheric ozone links air pollution & climate change (1) primary constituent of smog in surface air [NRC, 1991] (2) 3rd most important greenhouse gas [IPCC, 2001] O3 greenhouse gas Free Troposphere hn NO NO2 Hemispheric Pollution OH HO2 Boundary layer (0-2.5 km) Direct Intercontinental Transport VOC, CH4, CO air pollution (smog) NOx NMVOCs O3 NOx NMVOCs O3 air pollution (smog) OCEAN CONTINENT 1 CONTINENT 2