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Reviewing IMPROVE aerosol data, visibility parameters, equations, and monitoring for Regional Haze Rule compliance. Analyzing 2002 data, defining visibility aspects, and preparing next steps. Learn about extinction/scattering/absorption metrics, Deciview index, and practical applications.
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AoH Conference CallOctober 8, 2004 Air Resource Specialists, Inc.
Review of IMPROVE Aerosol Data • Visibility parameters and equations • IMPROVE monitoring • Regional Haze Rule data guidelines • Review of 2002 IMPROVE data (selected sites) • Next steps
Definitions of Visibility • Visual Qualities - The color, texture, and clarity of a scene • Visual Range (km) - The greatest distance at which a large black object on the horizon can be seen • Extinction/Scattering/Absorption (Mm-1) - The fraction of light lost per unit length along a sight path • Deciview (dv) - An index which is linear with human perception of visibility
Visibility Equations • Extinction is the sum of particle scattering, natural atmospheric scattering, and absorption: bext = bsp + bRayleigh + babs • Extinction can be converted into Visual Range or Deciview: Visual Range (km) = 3912 / bext Deciview (dv) = 10 x ln (bext / 10)
IMPROVE Extinction Equation • bext (Mm-1) = 3 * f(RH) * [Ammonium SULFATE] • + 3 * f(RH) * [Ammonium NITRATE] • + 4 * (1.4) * [ORGANIC CARBON] • + 10 * [ELEMENTAL CARBON] • + 1 * [SOIL] • + 0.6 * [COARSE MASS] • + Rayleigh scattering (typically use 10 Mm-1) • Where: • f(RH) is the relative humidity enhancement factor • Elemental carbon is the only species which absorbs light
IMPROVE Aerosol Sampler Systems • Sulfur>>Sulfate • Soil • PM2.5>> • Coarse Mass • Nitrate • Sulfate • (backup) • Organic Carbon • Elem. Carbon • PM10>> • Coarse Mass
Regional Haze Rule Data Guidelines • Calculate extinction based on IMPROVE equation, using 6 species and monthly f(RH) • Allowed to fill in missing species data with quarterly median values if strict conditions are met • Data completeness: • 50% for all quarters • 75% for the year • No more than 10 consecutive samples missing in a year • Minumum of 3 complete years needed to represent 5 year average • Convert extinction to deciview • Calculate annual 20% best and worst deciview averages
IMPROVE Total Aerosol ExtinctionWorst 20% for 2002 VIEWS web site: http://vista.cira.colostate.edu/views/Web/AnnualSummary/ContourMaps.aspx
IMPROVE Ammonium Sulfate ExtinctionWorst 20% for 2002 VIEWS web site: http://vista.cira.colostate.edu/views/Web/AnnualSummary/ContourMaps.aspx
IMPROVE Ammonium Nitrate ExtinctionWorst 20% for 2002 VIEWS web site: http://vista.cira.colostate.edu/views/Web/AnnualSummary/ContourMaps.aspx
IMPROVE Organic Mass ExtinctionWorst 20% for 2002 VIEWS web site: http://vista.cira.colostate.edu/views/Web/AnnualSummary/ContourMaps.aspx
2002 Data from Selected Sites • Timeline species extinction plots for 6 sites across WRAP: • Spokane Indian Reservation, WA • Medicine Lake, MT (adjacent to Fort Peck) • Rocky Mountain NP, CO • Grand Canyon NP, AZ • Yosemite NP, CA • Crater Lake, OR
Crater LakeRecon. Aerosol Extinction Comparison Avg. extinction: 48.9 Mm-1 Avg. extinction: 24.8 Mm-1
Crater LakeRecon. Aerosol Extinction Comparison Avg. extinction: 24.8 Mm-1 Avg. extinction: 23.9 Mm-1
Grand CanyonRecon. Aerosol Extinction Comparison Avg. extinction: 23.4 Mm-1 Avg. extinction: 21.8 Mm-1
Next Steps • Conference call week of October 18 • Working with RMC to transfer emission and TSSA data files to ARS • Begin adding draft documents to the AoH web site (introductory materials first) • Prepare samples of CIA reports on AoH web site (currently based on available data) • Review agenda for November meeting