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Nutrient Export Coefficient Modeling in Mediterranean Coastal Streams. Timothy H. Robinson, Al Leydecker, Arturo A. Keller and John M. Melack Bren School of Environmental Science & Management University of California, Santa Barbara, USA. UC Marine Council. Santa Barbara Coastal
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Nutrient Export Coefficient Modeling in Mediterranean Coastal Streams Timothy H. Robinson, Al Leydecker, Arturo A. Keller and John M. Melack Bren School of Environmental Science & Management University of California, Santa Barbara, USA UC Marine Council Santa Barbara Coastal LTER - NSF
SF LA Study Area Watershed Characteristics
Specifics: Analyzing for: Ammonium (NH4+), Nitrate (NO3-), Total Dissolve Nitrogen (TDN), Phosphate (PO43-), Total Particulate Carbon (TPC), Total Particulate Nitrogen (TPN), Total Particulate Phosphate (TPP), Total Suspended Sediments (TSS) and major ions at selected locations • Frequency: • Regular sampling: • Once every 2 weeks during the dry season • Once a week during the wet season • Storm sampling: • Every hour on the rising limb of the hydrograph • Every 2-4 hours on the falling limb of the hydrograph Project duration: WY2001, WY2002 and WY2003
E A GIS Datm LTER Datm Literature I Interview I Literature K Literature L S+P k t d/v a LU GIS Nutrient Export Coefficient Model (NEC-M) • Abbreviation key: • L – Nutrient Export (loss) (mass area-1 time-1) • E – Export Coefficient Function • b – Watershed Response Variable • LU – Land use • S – Soils • P – Precipitation • A – Land Use Area • I – Nutrient input rate • K – Down Stream Distance-Decay Function • k and a – Coefficients • t – Time • d – Distance Traveled Downstream • v – Average Velocity Traveled • Downstream • Datm – Atmospheric deposition
Sampling Site Locations WY2001 WY2002 WY2003 • Land Use: • Chaparral/Forest • Avocado • Greenhouse • Nursery • Residential • Commercial
Nutrient Export WY2002 • Hourly time-step • Hydrology: • Pressure Transducer • Observed stage • HEC-RAS • Stream Chemistry • Modeling
E S+P LU GIS Nutrient Export Coefficient (E) Franklin Creek E – Export Coefficient Function b – Watershed Response Variable S – Soils P – Precipitation
Scaling the Export Coefficient (b) • Storm to Storm relationships. • Volume Weighted Mean Concentrations vs. Cumulative Rainfall. • Volume Weighted Mean Concentrations vs. Rainfall/Runoff Ratio. • Topographic Index (TI): variable source area. • Antecedent Soil Moisture Content: SSURGO soils data, texture->porosity, infiltration rates, evapotranspiration rates, depth to impervious layer, etc.
Conclusions • High frequency storm sampling is critical. • Nutrient Export Coefficients in Mediterranean climates must be a function that is related to the watershed runoff response and not a single annual term. • Analysis of the final year of data will solidify scaling techniques in NEC-M. • Future work: implement the model in the study watersheds and test its portability in a catchment outside of the area (e.g. Spain).
Questions Thank you !
Linkage – Stream Network & Chemistry • Arc Hydro Geodatabase:geometric network representation of the connectivity of surface water • HydroNetwork • HydroEdge • HydroJunctions • SchematicLinks+Nodes • HydroPointEvent • HydroLineEvent Drainage Network + Sampling Points DEM analysis MS Excel/Access: Visual Basic for Application:
Measuring Stream Flow Staff Gauges and Pressure Transducers Surveying the Cross-Sections Developing Rating Curves
Nutrient Loading Development of a Nutrient Flux Model Stream Chemistry Observed Stage PT Stage (5-min) Stage-Discharge Relationship (HEC-RAS) Stream Chemistry Observed Flow PT Flow (5-min) Flow (hourly) Stream Chemistry (hourly) Observed Flow (hourly) Flow (hourly) Identify: Baseflow, Peakflow.. Nut. Conc. Stream Chemistry (model/obs) Flow (hourly) Linear extrapolation Annual Nutrient Loading Nut. Flux (conc/flow)
K Literature k t D/V a Attenuation (K) • Distance from stream • Distance from basin outlet • Type of riparian corridor • Dispersal Area and Trapping Likelihood (BI Index)
VWM vs. Cumulative Rainfall VWM - Volume Weighted Mean
VWM vs. Cumulative Rainfall VWM - Volume Weighted Mean