1 / 8

Recycling the Waste: The Development of a Catalytic Wittig Reaction

Recycling the Waste: The Development of a Catalytic Wittig Reaction. Angew. Chem. Int. Ed. 2009, 48 , 6836 –6839. Wittig reaction. The Wittig Reaction is a chemical reaction of an aldehyde or ketone with a triphenyl phosphonium ylide

sybill-carroll
Download Presentation

Recycling the Waste: The Development of a Catalytic Wittig Reaction

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Recycling the Waste: The Development of a Catalytic Wittig Reaction Angew. Chem. Int. Ed. 2009, 48, 6836 –6839

  2. Wittig reaction The Wittig Reaction is a chemical reaction of an aldehyde or ketone with a triphenyl phosphonium ylide (often called a Wittig reagent) to give an alkene and triphenylphosphine oxide

  3. (Br(Bu)2Te)2O Fig. (8). Catalytic formation of olefins according to experiments performed by Tang et al. [27] with Te based catalysts. Mini-Reviews in Organic Chemistry, 2004, Vol. 1, No. 1

  4. Scheme 1. Proposed catalytic Wittig reaction

  5. J. AM. CHEM. SOC. 2006, 128, 2394-2409

  6. Conclusions • The first Wittig reaction catalytic in phosphine has been developed. • A variety of heteroaryl, aryl, and alkyl aldehydes could be efficiently converted to the corresponding alkenes in moderate to high yield with the utilization of the phosphine oxide precatalyst 1.

More Related