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Treatment Wetlands for the Oil & Gas Industry. Presented by: Scott Wallace, P.E. Mark Liner, P.E. Scott.Wallace@naturallywallace.com (612) 802-2329 Mark.Liner@naturallywallace.com (651) 269-8201. References for Industrial Wetland Design. Water Environment Research Foundation (WERF)
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Treatment Wetlands for the Oil & Gas Industry Presented by: Scott Wallace, P.E. Mark Liner, P.E. Scott.Wallace@naturallywallace.com (612) 802-2329 Mark.Liner@naturallywallace.com (651) 269-8201
References for Industrial Wetland Design • Water Environment Research Foundation (WERF) • Small Scale Constructed Wetland Systems (Wallace & Knight, 2006) • Treatment Wetlands 2nd Edition • (Kadlec & Wallace, 2009)
Recent Industrial Wetland Examples • BP, Casper Wyoming Refinery, USA • BP, Lima Ohio, USA • ARCO Wellsville New York Refinery USA • Magellan Pipeline, (Watertown, South Dakota) USA • El Paso Energy (El Dorado, Kansas) USA • Buffalo-Niagara International Airport, USA • Heathrow Airport, London UK • Edmonton Airport, Alberta, Canada • Occidental Petroleum, Cano Limon, Colombia • Rosebel Gold Mine, Suriname • AIMC Gold Mine, Azerbaijan
Industries Using Wetlands • Oil & Gas (upstream & downstream) • Chemical Manufacturing • Landfills • Mining • Food Processing • Airports
Types of Treatment Wetlands • Surface Flow (SF) • Horizontal Subsurface Flow (HSSF) • Vertical Flow (VF) • Sludge Dewatering Reed Beds • Intensified Wetlands • Aerated (cold climates) • fill-and-drain (warm climates) • reactive media (ammonia, phosphorus, etc) • industrial wastewaters
Surface Flow Wetlands Kadlec & Wallace, 2008
Surface Flow Wetlands Champion Paper, Pensacola Florida
Horizontal Subsurface Flow Wetlands Wallace & Knight, 2006
Horizontal Subsurface Flow Wetland Wildflower Meadows: 90-person treatment system
Vertical Flow Wetland IWA, 2000
Vertical Flow Wetland Rousillon, France
Sludge Dewatering Reed Bed Skovby, Denmark: 8000-person treatment wetland Kadlec & Wallace, 2008
Main Treatment Mechanisms • Adsorption of dissolved-phase hydrocarbons • Contaminant retention time much greater than hydraulic retention time • Microbial degradation of organic compounds • Settling of particulate compounds • Oxidation and reduction of nitrogen compounds • Precipitation of metals • Use of intensification methods (aeration and reactive medias to accelerate treatment)
Treatment Wetland Design Basis • Tanks-in-series, N typically ranges from 3 to 6 • Value of N is different for reactive chemicals vs. tracers • Spatial variability of biodegradation rate represented by P • Important for complex organic chemistries (such as produced waters
Wetland Water Balance • Sum of water entering and exiting the wetland from all sources Kadlec & Knight, 1996
Climate Range of Treatment Wetlands Wellsville, New York Northern Sahara, Libya
Wetland Energy Balance • Sum of energy gains and losses from all sources Kadlec & Knight, 1996
Water Balance and Energy Balance are Closely Inter-related • Warm arid climates large water losses due to ET • Monsoon climates large water gains in the rainy season • Cold climates ice formation
Wetland Plants Kadlec & Wallace, 2009
Role of Plants in Treatment Wetlands • Surface area for attached growth of bacteria • Shade the water column (reduced algae) • Minimize mixing effects in open-water systems • Increased microbial diversity • Oxygen transport through roots (small effect)
Wetland Plant Selection Wallace & Knight, 2009
Natural vs. Mechanical Systems Energy and O&M Needs LEAST MOST Mechanical Treatment Systems Intensified Wetlands Natural Systems Area Requirements MOST LEAST
Casper, Wyoming Casper
BP – Casper, Wyoming Refinery • Operated 1912 to 1991 • 37,000 m3 of LNAPL recovered to date • Extensive smear zone due to river flooding • 50 to 100 years to remediate site • High mountain west: -35oC
Casper Reuse Plan HSSF Wetlands SF Wetlands
Casper Pilot Wetland System • 4 cells • With and without insulating mulch • Vertical upward flow • With and without aeration Phytokinetics, Inc.
Casper Rate Coefficients kA, m/yr, based on 3 TIS Wallace & Kadlec, 2005
Full-Size System from Pilot Data Wallace & Kadlec, 2005
Casper Benzene Data 2004 - 2006 Benzene effluent at Outfall 001 consistently below detection levels <0.01 mg/L
Buffalo, New York Buffalo
Treatability Testing • Measure glycol degradation in both warm and cold temperatures • With and without aeration
Comparing Treatment Effectiveness • Aerated rate coefficient: 5.30 d-1 • Non-aerated rate coefficient: 0.55 d-1 • An aerated wetland is 10X more effective in treating glycol
Vertical Flow with Aeration Water Level Mulch Layer Influent Line Drain Line Air Line