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Acid-Base reactions. CH 3 CO 2 H(aq) + NaOH(aq) 1. CH 3 CO 2 H 2 + (aq) + NaO(aq) 2. CH 3 CO 2 - (aq) + H 2 O(l) + Na + (aq) 3. CH 4 (g) + CO 2 (g) + H2O(l). Acid-Base reactions. HCN(aq) + NH 3 (aq) 1. NH 4 + (aq) + CN - (aq)
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Acid-Base reactions CH3CO2H(aq) + NaOH(aq) 1. CH3CO2H2+(aq) + NaO(aq) 2. CH3CO2-(aq) + H2O(l) + Na+(aq) 3. CH4(g) + CO2(g) + H2O(l)
Acid-Base reactions HCN(aq) + NH3(aq) 1. NH4+(aq) + CN-(aq) 2. H2CN+(aq) + NH2-(aq) 3. C2N2(s) + 3 H2(g)
Acid-Base Reactions:Find the hidden bases Thing to know: Anions of weak acids are bases. Example: CH3COOH = weak acid CH3COO- therefore = weak base HCN = weak acid CN- = weak base H3PO4 = weak acid PO43- = weak base
Return to Acid-Base Reactions:Find the hidden bases HCl + NaCN ? HCl + AlPO4 ? HCl + CaC2O4 ?
Precipitation Reactions Solubility of Ionic Compounds dissolving
To Determine Solubility: 1. identify the two ions 2. soluble ions with no “exceptions” never form precipitates 3. use listing under soluble/insoluble, but check to see if it’s an exception
Examples Soluble or Insoluble? • NaNO3 • FeCl3 • Fe(OH)3 • BaSO4 • AgNO3 • AgCl
More Examples Soluble or Insoluble? • K3PO4 • Fe3(PO4)2 • PbCl2 • FeSO4 • (NH4)2S • PbS
PRS Example 1 Which of the following is soluble? • AlPO4 • PbBr2 • Al(OH)3 • FeSO4
PRS Example 2 Which of the following is insoluble? • Al(NO3)3 • PbC2O4 • NaOH • FeF3
Precipitation ReactionsNet Ionic Equations Pb(NO3)2 + K2CrO4 ? Pb(NO3)2 + KI ? BaCl2 + KNO3
Gas Forming Reactions 2 H+ + CO32- CO2(g) + H2O(l) 2 H+ + SO32- SO2(g) + H2O(l) 2 H+ + M H2(g) + M2+(aq) M = metal, like Mg or Fe