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MINERALS AND ROCKS IN THE EARTH’S CRUST. Igneous, Sedimentary, Metamorphic Rocks and Environments. MINERALS AND ROCKS COME FROM ELEMENTS. Chemical elements are the fundamental materials of which all matter is composed. From the modern viewpoint:
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MINERALS AND ROCKS IN THE EARTH’S CRUST Igneous, Sedimentary, Metamorphic Rocks and Environments
MINERALS AND ROCKS COME FROM ELEMENTS • Chemical elements are the fundamental materials of which all matter is composed. • From the modern viewpoint: • a substance that cannot be broken down or reduced further
MAKING MINERALS FROM ELEMENTS • ALMOST ALL THE MINERALS FOUND IN THE EARTH ARE FORMED FROM THE BONDING OF EIGHT (8) ELEMENTS • OXYGEN (O) • SILICON (Si) • ALUMINIUM (Al) • IRON (Fe) • CALCIUM (Ca) • POTASSIUM (K) • SODIUM (Na) • MAGNESIUM (Mg) MOST ABUNDANT LEAST ABUNDANT
WHAT ARE MINERALS? • BUILDING BLOCKS FOR ROCKS • DEFINITION: • NATURALLY OCCURRING, • INORGANIC SOLIDS, • CONSISTING OF SPECIFIC CHEMICAL ELEMENTS, AND • A DEFINITE ATOMIC ARRAY • CRYSTALLINE STRUCTURE – ‘CRYSTAL’ • ‘CRYSTAL’ AND ‘MINERAL’ INTERCHANGEABLE TERMS
MINERALS Minerals divided into two main groups based on Silica content Silica (SiO) compound of molecularly bonded silicon (Si) and oxygen (O) molecules (SiO, SiO2, SiO4, SiO6 etc.) GROUP 1: SILICATES – CONTAIN SILICA GROUP 2: NON-SILICATES (CONTAIN NO SILICA)
NON-SILICATE MINERALS • Non-silicate minerals are very rare • Make up 5% of Earth’s continental crust • Considered valuable commercially as building materials, gemstones, iron ores for steel, ceramics, and more. • Native metals: gold, silver, copper, platinum • Native elements: diamonds, corundum: Ruby (red) or Sapphire (blue) • Carbonates: calcite (used in cement) • Oxides: hematite (iron ores) • Sulfides: galena (lead ores) • Sulfates: gypsum (used in plaster, dry wall) • Halides: halite (table salt)
SILICATE MINERALS • THE MOST ABUNDANT OF ALL MINERALS • MAKE UP APPROXIMATELY 95% OF WEIGHT OF EARTH’S CRUST • CONTAIN VARYING AMOUNTS OF SILICA (SiO) • DOMINANT COMPONENT OF MOST ROCKS: • IGNEOUS • SEDIMENTARY • METAMORPHIC
SILICATE MINERALS • LISTED BELOW IN DECREASING % OF SILICA ARE MOST COMMON SILICATE MINERALS • QUARTZ (SiO2) (“High” Silica content ~100%) • FELDSPARS (PLAGIOCLASE - (Na,Ca)(Si,Al)4O8 ) • MICAS (MUSCOVITE -KAl2(AlSi3O10)(F, OH)2 and BIOTITE - K (Fe, Mg)3 AlSi3 O10 (F, OH)2 ) • AMPHIBOLES (Hornblende -Ca2(Fe,Mg)5Si8O22(OH2) • PYROXENES (Augite – (Mg,Fe) SiO3) • OLIVINE - (Mg, Fe)2SiO4, (“Low” Silica content ~40%)
SILICATE MINERALS • SILICATE MINERALS ARE BROKEN INTO THREE MAIN GROUPS ACCORDING TO % SILICA • FELSIC High percent • MAFIC • ULTRAMAFIC Low percent
FELSIC SILICATE MINERALS • FELSIC SILICATE MINERALS HAVE A HIGH CONCENTRATION OF SILICON, OXYGEN, ALUMINIUM AND POTASSIUM • FELSIC SILICATES – HIGH % SiO (75-100%) • QUARTZ (100% SiO2) • FELDSPARS (Plagioclase, Orthoclase) • MUSCOVITE MICA
QUARTZ FELDSPAR MUSCOVITE MICA
MAFIC SILICATE MINERALS • MINERALS WITH HIGH CONCENTRATION OF MAGNESIUM AND IRON, PLUS CALCIUM AND SODIUM, AND LOWER AMOUNTS OF SILICON AND OXYGEN • MAFIC SILICATES - LESS SiO (50-60%) • BIOTITE MICA • AMPHIBOLE (Hornblende) • PYROXENE (Augite)
BIOTITE MICA PYROXENE (AUGITE) AMPHIBOLE (HORNBLENDE)
ULTRAMAFIC SILICATES • MINERALS WITH GREATER CONCENTRATION IN MAGNESIUM AND IRON. VERY RARE AT EARTH’S SURFACE • ULTRA MAFIC SILICATES - VERY LOW % SiO (less than 50%) • VERY RARE AT SURFACE • OLIVINE (FORSTERITE, FAYALITE)
WHAT ARE ROCKS? • AGGREGATIONS OF 2 OR MORE MINERALS • Same or different minerals combine together • THREE CATEGORIES • IGNEOUS • SEDIMENTARY • METAMORPHIC
IGNEOUS ROCKS • Ignis: Latin for “Fire” • FORMED FROM COOLED, SOLIDIFIED MOLTEN MATERIAL AT, NEAR, OR DEEP BELOW, THE SURFACE • TYPES: • PLUTONIC (INTRUSIVE) –IGNEOUS ROCKS COOLED AND SOLIDIFIED BELOW SURFACE AT GREAT DEPTHS • VOLCANIC (EXTRUSIVE) – IGNEOUS ROCKS COOLED AND SOLIDIFIED AT OR NEAR THE SURFACE THROUGH VOLCANIC ERUPTIONS
IDENTIFICATION OF IGNEOUS ROCKS • TWO IDENTIFICATION PROCESSES FOR PLUTONIC OR VOLCANIC IGNEOUS ROCKS: • TEXTURE: • Size, shape and manner of growth of individual crystals • MINERAL COMPOSITION • Based on SiO content • Felsic, Intermediate, Mafic • (high Silica low Silica)
TEXTURE IDENTIFICATION • SIZE, SHAPE OF CRYSTALS AND MANNER OF GROWTH • FINE GRAINED TEXTURE: • VERY TINY, MINERAL CRYSTALS VISIBLE ONLY WITH MAGNIFICATION • INDICATES FAST COOLING AT SURFACE – CRYSTALS SOLIDIFIED QUICKLY WITH NO TIME TO ‘GROW’ • COARSE-GRAINED TEXTURE: • LARGE, EASILY-VISIBLE MINERAL CRYSTALS • INDICATES SLOW COOLING AT DEPTH – CRYSTALS SOLIDIFIED SLOWLY WITH LOTS OF TIME TO ‘GROW’
TEXTURE IDENTIFICATION Fine-Grained Textures Coarse-Grained Textures
MINERAL COMPOSITION • CLASSIFIED BY SILICA (SiO) CONTENT • FELSIC – MORE THAN 85% SILICA • INTERMEDIATE – 60-85% SILICA • MAFIC – LESS THAN 60% SILICA
MINERAL COMPOSITION OF COMMON IGNEOUS ROCKS • FELSIC IGNEOUS ROCKS (>85% SiO) • GRANITE: • PLUTONIC-INTRUSIVE; PHANERITIC TEXTURE; FELSIC MINERAL COMPOSITION • RHYOLITE: • VOLCANIC-EXTRUSIVE; APHANITIC TEXTURE; FELSIC MINERAL COMPOSITION • INTERMEDIATE IGNEOUS ROCKS (60-85% SiO) • DIORITE: • PLUTONIC-INTRUSIVE; PHANERITIC TEXTURE; INTERMEDIATE MINERAL COMPOSITION • ANDESITE: • VOLCANIC-EXTRUSIVE; APHANITIC TEXTURE; INTERMEDIATE MINERAL COMPOSITION • MAFIC IGNEOUS ROCKS (<60% SiO) • GABBRO: PLUTONIC- • INTRUSIVE; PHANERITIC TEXTURE; MAFIC MINERAL COMPOSITION • BASALT: • VOLCANIC-EXTRUSIVE; APHANITIC TEXTURE; MAFIC MINERAL COMPOSITION
FELSIC IGNEOUS ROCKS RHYOLITE EXTRUSIVE INTRUSIVE GRANITE
INTERMEDIATE IGNEOUS ROCKS ANDESITE EXTRUSIVE DIORITE INTRUSIVE
MAFIC IGNEOUS ROCKS GABBRO INTRUSIVE BASALT EXTRUSIVE
OTHER IGNEOUS ROCKS • VOLCANIC GLASS: • OBSIDIAN: VOLCANIC-EXTRUSIVE; NO CRYSTALS FORM; SILICA-RICH, COOLED INSTANEOUSLY • PUMICE: VOLCANIC-EXTRUSIVE; NO CRYSTALS FORM; SILICA-RICH; SOLIDIFIED FROM ‘GASSY’ LAVA • PYROCLASTIC ROCKS • TUFF: VOLCANIC-EXTRUSIVE; SOLIDIFIED ‘WELDED’ ASH
VOLCANIC GLASS OBSIDIAN PUMICE
PYROCLASTIC IGNEOUS ROCKS WELDED TUFF
SEDIMENTARY ROCKS • WEATHERING PROCESSES BREAK ROCK INTO PIECES, SEDIMENT. • READY FOR SEDIMENTATION PROCESSES: • TRANSPORTATION DEPOSITION BURIAL AND LITHIFICATION INTO NEW ROCKS.
SEDIMENTARY PROCESSES • LITHIFICATION: • As sediment is buried several kilometers beneath the surface, heated from below, pressure from overlying layers, heat, and chemically-active water converts the loose sediment into solid sedimentary rock • Compaction - volume of a sediment is reduced by application of pressure • Cementation - sediment grains are bound to each other by materials originally dissolved during chemical weathering of preexisting rocks • typical chemicals include silica and calcium carbonate.
CLASSIFYING SEDIMENTARY ROCKS • THREE SOURCES FOR SEDIMENTARY ROCKS • Detrital (or clastic) sediment is composed of transported solid fragments (or detritus) of pre-existing igneous, sedimentary or metamorphic rocks • Chemical sediment forms from previously dissolved minerals that either precipitated from solution in water, or were extracted from water by living organisms • Organic sedimentary rock consisting mainly of plant remains
CLASTIC/DETRITAL SEDIMENTARY ROCKS • CLASSIFIED ON GRAIN OR PARTICLE SIZE • Shales: finest-grained • Sandstones: medium-grained • Conglomerates – Breccias: coarse-grained
SHALES : CLASTIC SEDIMENTARY • SHALES: finest-grained clastic sedimentary rocks – composed of very small particles (from <0.004-0.063 mm) • 50% of all sedimentary rocks are Shales • Consist largely of Clay minerals (weathered granite in many cases) • Subcategories: Claystones; Siltstones; Mudstones • Economic value: building material; china and ceramics; spark plug housings
SHALES Burgess Shale in Canada Limestone on black shale
MUDSTONES, SILTSTONES Identified by decreasing amounts of sand and increasing amounts of clay
SANDSTONES • SANDSTONES: medium-grained clastic sedimentary rocks; particle-size (0.063-2 mm) • 25% of all sedimentary rocks fall into this category • Economic value: glass; natural reservoirs for oil, gas, and groundwater
CONGLOMERATES - BRECCIAS • CONGLOMERATESAND BRECCIAS: • The coarsest of all the clastic sedimentary rocks • Composed of particles >2 mm in diameter • Conglomerate - the particles are rounded • Breccia - the particles are angular
CHEMICAL SEDIMENTARY ROCKS • TWO CATEGORIES: • INORGANIC CHEMICAL SEDIMENTARY • ORGANIC CHEMICAL SEDIMENTARY
INORGANIC CHEMICAL SEDIMENTARY ROCKS • Formed when dissolved products of chemical weathering precipitate (‘form out of’) from solution • Most common types: • Inorganic limestones and cherts: precipitates directly from seawater and fresh water • Evaporites: precipitates when ion-rich water evaporates • Dolostones: Origin is still in debate
INORGANIC - LIMESTONES • Limestones -account for 10% - 15% of all sedimentary rocks formed from Calcite or Calcium Carbonate (CaCO3). • Formed as pure carbonate muds accumulate on the sea floor • Also formed on land: • Tufa - a soft spongy inorganic limestone that forms where underground water surfaces • Travertine - forms in caves when droplets of carbonate-rich water on the ceiling, walls and floors precipitate a carbonate rock: stalactites and stalagmites
LIMESTONES TRAVERTINE
ORGANIC LIMESTONES • Formed with calcite from marine environment: CaCO3 shells and internal/external skeletons of marine animals • Coquina - “crushed” shell fragments cemented with CaCO3 • Chalk - made from billions of microscopic carbonate- secreting organisms • Coral Reefs - Formed from the skeletons of millions of tiny invertebrate animals who secrete a calcite-rich material. Live “condo” style while algae acts as the cement to create the large structures called “reefs”. • Organic Chert - formed when silica-secreting microscopic marine organisms die (radiolaria {single-celled animals} and diatoms {skeletons of singled-celled plants}) • Flint - an example of an Inorganic Chert
COQUINA, CHALK AND FOSSILIFEROUS LIMESTONES COQUINA FOSSILIFEROUS LIMESTONE CHALK
ORGANIC SEDIMENTARY ROCKS • Coal - Organic sedimentary rock consisting mainly of plant remains • Formation: • Burial of decaying vegetation; • Increasing pressure from the overlying layers expels water, CO2 and other gases; • Carbon accumulates. • STAGES: • Peat - formed early in the process, when the original plant structure • can still be distinguished. • Lignite - a more hardened form of Peat • Bituminous - more pressure and more heat produce this moderately • hard coal. • Anthracite - the hardest coal - formed from metamorphic processes • under extreme heat and pressure - Hard - Shiny - the most • desired as an energy resource.
COAL PEAT LIGNITE ANTHRACITE BITUMINOUS