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Chapter 17: Carbonyl Compounds Part II

Chapter 17: Carbonyl Compounds Part II. Reaction of Ketones and Aldehydes. Content. 17.1 Nomenclature of Aldehydes and Ketones. 17.2 How Aldehydes and Ketones React (Part I). 17.3 How Aldehydes and Ketones React (Part II). 17.4 How Aldehydes and Ketones React (Part III).

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Chapter 17: Carbonyl Compounds Part II

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  1. Chapter 17: Carbonyl Compounds Part II Reaction of Ketones and Aldehydes

  2. Content 17.1 Nomenclature of Aldehydes and Ketones 17.2 How Aldehydes and Ketones React (Part I) 17.3 How Aldehydes and Ketones React (Part II) 17.4 How Aldehydes and Ketones React (Part III) 17.5 The Wittig and Related Reactions 17.6 Nucleophilic Addition to a a and b b- Unsaturated Aldehydes and Ketones 2

  3. Learning Objectives 1. Recognize and assign names to aldehydes and ketones. 2. Write the mechanism for nucleophilic addition and nucleophilic addition-elimination reactions of aldehydes and ketones, and be able to predict the products of such reactions. 3. Be able to explain the relative reactivity of carbonyl compounds toward nucleophilic addition. 4. Be able to describe the concept of employing protecting groups. 5. Predict the products of the reactions of carbonyl compounds with Grignard reagents, hydride ion donors, sulfur nucleophiles, and with phosphonium ylides (the Wittig reaction). 6. Be able to recognize Re and Si faces of carbonyl compounds, and the stereochemistry outcomes from a nucleophilic addition. 7. Predict the products of addition reactions to a,b-unsaturated carbonyl compounds. 3

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