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This report provides data on limit values and environmental performance for large combustion plants and chlor-alkali manufacturing. It compares these values to the best available techniques and includes information on emissions to air and water.
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Implementation of the IPPCD – Data on ELV and BAT DG ENV, Brussel, 7 December 2010
Outline • Introduction • Large combustion plants • General information • Emission sources to air • Emission sources to water • Chlor-alkali manufacturing • General information • Emission sources to air • Emission sources to water • General considerations
Introduction “Provide available representative data on the limit values and environmentalperformancelaid down by a specific category of activities […] and, if apropriate, the best available techniques from which those values are derived. Describe how these data have been chosen and collected.” “[…] The reported data (on emission limit values and environmental performance) will be assessed to compare, as far as possible, the limit values set and the performanceachieved. A comparison could then be done with the BAT-associated emission levels in BREFs.” • Focus on two IPPC activities: • Large combustion plants (LCP) • Chlor-alkali manufacturing
Introduction - LCP • Scope of report • Combustion activity • Producing electricity (including CHP) • Using solid or liquid fuels • Selection of installations: • Maximum of 6 installations per MS • Selection based on the emission inventories • 3 capacity classes: 50 – 100 MWth 100 – 300 MWth two top NOx emitters per class > 300 MWth • Emissions • To air • To water from waste gas treatment
Large Combustion Plants • 113installations reported • Only 7new installations • Covers25Member States • 203combustion plants/emission sources to air reported
160selected emission sources for further analysis covers 24Member States
Large Combustion Plants 61% with capacity > 300 MWth 64% burning coal/lignite 160emission sources to air Only8% burning biomass 79plants use CHP
Large Combustion Plants – ELVs vs. BAT AELs • Averaging period: BAT AEL Only ± 20% of reported ELVs DAV All ELVs included • Reference oxygen content recalculated when different
Large Combustion Plants – ELVs vs. BAT AELs • CO • ELVs reported for 50% of the emission sources • BAT AELs not as clearly defined as for other pollutants • Comparison with values mentioned: similar result as for other pollutants etc. • Mercury • ELVs reported for 19% of the emission sources • 9 Member States reported ELVs • No BAT AELs mentioned in BREF for comparison
Large Combustion Plants – Actual emissions Actual emissions • Reference year for emissions: 2006, 2007 or 2008 • Expressed as average of all measured values • Reference oxygen content recalculated when different • Compared to ELVs (when reported) BAT AELs from the BREF LCP
Large Combustion Plants – BAT End-of-pipe SO2 NOx End-of-pipe Primary Primary Dust
Large Combustion Plants 57% with capacity > 300 MWth Waste water 70emission sources with from flue gas cleaning coal/lignite, liquid, biomass 91emission sources to water BAT AEL ~ emission levels associated with BAT FGD (DAV) Averaging periods
SS (mg/L) COD (mg/L) Nitrogen compounds (mg/L) Sulphate (mg/L)
Large combustion plants - BAT Emission prevention and abatement techniques • Reported for 24plants
Introduction – Chlor-alkali • Scope of report • Chlor-alkali manufacturing installations • Different production processes, i.e. • Diaphragm cell process • Asbestos diaphragm cell process • Selection of installations • Maximum of 10 installations per MS • Priority to installations using • Mercury cell process • Asbestos diaphragm cell process • Emissions • To air • To water • Membranecellprocess • Mercurycellprocess
Chlor-alkali manufacturing • 61installations reported 77 chlor-alkali production units • Only 2new installations • Covers 18member states • 103emission sources to air • 65emission sources to water
Chlor-alkali manufacturing Asbestos diaphragm or mercury cell process 63% will convert to membrane cell process Closure is reported for 16% of the production units 21% of the units reported ‘other’ 64% of total capacity (55% of production units) converts by 2019-2020 An earlier conversion was reported for 19 installations 24 installations already closed mercury cell productions Conversionorclosure?
General considerations • Confusion about different concepts Installation Combustion plant Emission source • Averaging periods • LCP emission sources to water related to flue gas cleaning?