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CE3503 Environmental Engineering. Air Quality and Pollution Control. Dr. Martin T. Auer MTU Department of Civil & Environmental Engineering. Composition of Clean, Dry (“Pure”) Air. Nitrogen 78.08 % Oxygen 20.95 Argon 0.93 Carbon dioxide 0.03
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CE3503 Environmental Engineering Air Quality and Pollution Control Dr. Martin T. Auer MTU Department of Civil & Environmental Engineering
Composition of Clean, Dry (“Pure”) Air Nitrogen 78.08 % Oxygen 20.95 Argon 0.93 Carbon dioxide 0.03 Neon 18.0 ppm (= 18x10-4 %) Helium 5.2 Methane 1.8 Krypton 1.1 Hydrogen 0.5 Nitrous oxide 0.3 Ozone 0.01 Source: Carnegie Mellon University; Environmental Decision Making, Science & Technology
Oxides of Sulfur COO- C CH2 SH H NH3+ Source: fossil fuels http://www.fieldmuseum.org/research_collections/ecp/ecp_sites/NPI_web/models_coal.htm cystine
Oxides of Sulfur Source: roasting mineral ores International Nickel mines and processes nickel sulfide ores in Sudbury, Ontatio. The Inco Superstack, with a height of 380 m (1,247 ft), is the tallest chimney in the Western hemisphere and the second tallest freestanding chimney in the world after the GRES-2 Power Station in Kazakhstan. http://www.flickr.com/photos/23510510@N03/2687642620/
Oxides of Nitrogen Nitrogen dioxide http://www.uncp.edu/home/mcclurem/ptable/co.htm Smog event in Santiago, Chile
CO: Concentration / Exposure Figure 11.10: Effect of carbon monoxide on health (After W. Agnew. 1968. Proceedings of the Royal Society A307:153.)
Lead http://www.soe.wa.gov.au/report/atmosphere/outgoing-issue-lead.html Atmospheric lead compared with the exposure standard in Perth, Australia. Lead-based paints were phased out in the 1970s and lead was reduced and then removed from gasoline in the 1980s and 1990s.
Time Course of Ozone Formation 0.6 hydrocarbons, HC (traffic) 0.5 0.4 ozone, O3 (photochemical reaction) 0.3 Concentration (ppm) nitrogen dioxide, NO2 (reaction) nitric oxide, NO (traffic) 0.2 0.1 0.0 4 6 8 10 12 14 16 18 Time of Day Source: Carnegie Mellon University; Environmental Decision Making, Science & Technology
SUPERADIABATIC (ambient air is cooling faster than 1°C per 100m) stack ambient Elevation (m) adiabatic lapse rate superadiabatic lapse rate Temperature (°C)
SUBADIABATIC (ambient air is cooling slower than 1°C per 100m) ambient stack Elevation (m) adiabatic lapse rate subadiabatic lapse rate Temperature (°C)
INVERSION (warm air mass over cold air mass) stack ambient Elevation (m) adiabatic lapse rate inversion Temperature (°C)
Inversion http://www.stuffintheair.com/weather-inversions.html
Air Quality Index http://www.deqmiair.org/index.cfm?page=home&sFlush=no
Figure 12.3: Bag filter used for control of particulate air pollutants
Figure 12.5: Electrostatic precipitator used for control of particulate air pollutants
Figure 12.9: The effectiveness of various air pollution control devices depends on particle size.
Catalytic Converter Noble metals: resistant to corrosion, e.g. platinum and palladium
Gaia Hypothesis The Gaia Hypothesis, formulated by James Lovelock in the mid-1960s, proposes that our planet functions as a single organism that maintains conditions necessary for its survival.