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MRSM PENGKALAN CHEPA CHEMISTRY UNIT 2013

MRSM PENGKALAN CHEPA CHEMISTRY UNIT 2013. GUIDELINES FOR ANSWERING PAPER 3. Structure Question NO 1 or NO 2 is to test the mastery of 11 Scientific Skills 1. Observing 2. Classifying 3. Inferring 4. Measuring (burette , stopwatch, thermometer, voltmeter)

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MRSM PENGKALAN CHEPA CHEMISTRY UNIT 2013

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  1. MRSM PENGKALAN CHEPACHEMISTRY UNIT2013 GUIDELINES FOR ANSWERING PAPER 3

  2. Structure Question NO 1 or NO 2 is to test the mastery of 11 Scientific Skills 1. Observing 2. Classifying 3. Inferring 4. Measuring (burette , stopwatch, thermometer, voltmeter) 5. Predicting 6. Communicating( e.g construct table and draw graph) 7. Space-Time Relationship 8. Interpreting Data 9. Defining Operationally 10. Controlling Variables 11. Hypothesizing

  3. Operational definition is a statement that contains: 1. what you do/procedure 2. what you see/observation Examples 1. State OD for coagulation of latex When acid is added into latex, white solid is formed- correct (When acid is added into latex, latex coagulated.- wrong)

  4. 2. State Op Deffor rate of reaction in this experiment When the higher concentration sodium thiosulphate solution is added into sulphuric acid, time taken for `X~ mark to disappear from sight is shorter.

  5. 3. State Op Deffor rusting of iron When iron nail is coiled with copper and immersed into jelly mixed with potassium hexacyanoferrate(III) and phenolphthalein solution, blue spot/colouration is formed.

  6. More examples on Operational definition What you do - What is observed 1. Rusting of iron - When an iron nail coiled with a less electropositive metal is immersed in hot agar-agar added with potassium hexacyanoferrate (III) solution, blue spots are formed

  7. More examples on Operational definition What you do - What is observed 2. Coagulation of latex - When acid is added to latex White solid is formed

  8. 3. Reactivity of Group 1 elements When a metal which is lower in Group 1 is put in a basin half filled with water brighter flame is formed 4. Precipitation of silver chloride When silver nitrate solution is added to sodium chloride solution White solid is formed

  9. 3. 5. Voltaic cell When two different metals are dipped into an electrolyte The needle of the voltmeter deflects//Voltmeter shows a reading

  10. More examples on Operational definition What you do What is observed 6. An acid When a blue litmus paper is dipped into a substance which is dissolved in water, blue litmus paper turns red

  11. More examples on Operational definition What you do What is observed 7. Heat of combustion When 1 mol of fuel is burnt in excess oxygen Temperature rises//Thermometer reading increases

  12. More examples on Operational definition What you do What is observed 8. Hardness of alloy When a weight is dropped on a steel ball bearing taped on an alloy block diameter of dent formed is smaller

  13. Hypothesis: ( early conclusion to aim of exp) • Statement that relates the MV followed by responding variable with direction. • Example: • The higher temperature of the reactant the higher the rate of reaction – 3 marks • 2. Hexenedecolourised brown bromine water but hexane does not

  14. Hypothesis: ( early conclusion to aim of exp) Statement that relates the MV followed by RV with direction. Example: 3. When acid is added into latex, latex coagulates, when ammonia is added into latex, latex cannot coagulates

  15. When size of calcium carbonate is smaller, the rate of reaction increases

  16. When hexene is added to bromine water, brown colour decolorized, but when hexane is added to bromine water, brown bromine not changed

  17. When no of carbon atoms per molecule alcohol increases, the heat of combustion increase

  18. When acid is added to latex, coagulation of latex occurs, but when ammonia solution is added to latex, NO coagulation occur

  19. How is the reading of apparatus taken? to 1 decimal point or 2 decimal point? 1.30 1.6 20.40 24.0

  20. STRUCTURE PAPER 32008

  21. 1 Diagram 1 shows three sets, Set I, Set II and Set III, of the apparatus set-up for an experiment to investigate the effect of ethanoic acid and ammonia solution on the coagulation of latex.

  22. Latex + ethanoic acid Latex coagulate Latex + not coagulate Latex + ammonia Latex only Latex coagulate

  23. (a) State one hypothesis based on Set I and Set II. Acid coagulate latex while alkali does not coagulate the latex

  24. (b) Record the time taken for the latex to coagulate in Set 1 and Set III. Set I : 5 minutes // 300 s Set III: 6 hours // 60 minutes// 21600 s

  25. (c) Construct a table to record the time taken for coagulation in Set I and Set III.

  26. (d) State one observation that can be obtained from each set of this experiment. Set I : Latex coagulates / A solid lump is formed Set II : Latex does not coagulate / No change / Liquid Set III : Latex coagulates / A solid lump is formed

  27. (e) State the operational definition for the coagulation of latex. When acid is added to latex, it becomes solid

  28. Ethanoic acid / Acid/(Ammonia solution) / Alkali (f) Manipulated variable: Responding variable : Constant variable : Coagulate //Time taken for coagulation Vol of latex / acid / (ammonia solution) / alkali // latex /temp

  29. (g) (i) Set II after 2:00 p.m. What observation can be made about the latex? Latex coagulates // Latex becomes solid/(semi-solid) //Latex is solidified

  30. bacteria in air reacts with latex to produce lactic acid ( H +) (ii) Explain the answer in l(g) (i). Hydrogen ions (H+ ) neutralise OH-ions in ammonia solution Hydrogen ions (H+ ) neutralised the negative charge of protein membrane, collisions of rubber particles occur, rubber molecules clump

  31. Bacteria in air reacts with latex to produce lactic acid / H+ • Explain why latex can coagulate without acid in Set III. These H+neutralise the negatively charged on the protein membrane of latex particles Latex particles no longer repel each other, so the particles collide, rubber molecules clump

  32. i) (i) Explain why the latex in Set I coagulates faster than the latex in Set III. The concentration of hydrogen ion, H+ in Set I is higher than in set III In set I , H+ produced, neutralise the negatively charged on the protein membrane faster than in set III

  33. (ii) The following is a list of chemical substances • Nitric acid • Sodium hydroxide • Methanoic acid • Potassium hydroxide Classify these substances into substances that can coagulate latex and substance that cannot coagulate latex.

  34. Potassium hydroxide Sodium hydroxide Nitric acid Methanoic acid

  35. SPM-P3 2009

  36. Exp 1: ELECTROLYSIS CuSO4 USING C AS ELECTRODE Exp 2: ELECTROLYSIS CuSO4 USING Cu AS ELECTRODE

  37. a. 3 obsvn and inference (not include the colour change of the electrolyte) inference Observations • Colourless gas bubbles released at anode Oxygen is produced • A brown solid is deposited at the cathode and the cathode thicker Copper is formed at the cathode

  38. a. 3 obsvn and inference (not include the colour change of the electrolyte) inference Observations Copper anode dissolves to form copper (II) ions • The copper anode in exp II become thinner

  39. b. State one hypothesis for the experiment In the electrolysis of copper(II) sulphate solution ,the types of products formed at the electrodes depend on the types of electrodes used

  40. Manipulated variable The type of electrodes used responding variable The products formed at anode Concentration of Copper(II) sulphate/ copper(II) sulphate Constant variable

  41. Sodium hydroxide • Nitric acid • Potassium iodide O2 I2 but iodine is denser than water, so does not bubble O2

  42. In cell I, the blue colour change to light blue.In cell II. No change of colour in the solution. Explain • In Cell I, • Blue colour is due to Cu 2+ ion. • Cu +2 are discharged to form Cu atoms at cathode. • (Cu 2++ 2e  Cu) • So conc of Cu+2 decrease.

  43. In cell I, the blue colour change to light blue.In cell II. No change of colour in the solution. Explain • In cell II, • Rate of ionization of copper atom to Cu+2 (CuCu2++2e) at anode is equal • to rate of discharge of Cu+2 to copper atoms ( Cu 2+ + 2e  Cu) at cathode. • So conc of Cu+2 remain constant

  44. Draw the diagram of electroplating of iron key with silver using silver nitrate solution Anode cathode Silver rod Iron key Silver nitrate solution

  45. SPM PAPER 3 STRUCTURES2010

  46. 13.0 13.1 13.0 I- Lithium burns with a white flame II- Potassium burns with a purple flame III- Sodium burns with a yellow flame

  47. 3 inferences from exp II • Potassium reacts vigorously • with water • alkaline solution is produced • Heat is released Hypothesis in this experiment • The lower the position elements in Group I, the higher the reactivity of metals with water

  48. e) State operational definition of of reactivity of Group I elements • When Group I elements are placed in water, • the intensity of the flame produced shows the reactivity of the elements

  49. Arrange in ascending order of reactivity • Li Na K Give reason in term of atomic size • Atomic size increase from lithium atom to potassium atom • Nuclei attraction in K atom is the most • K atom is the easiest to release electron to form K+ ion

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