1 / 29

Synthese von Sulfanilamid

Synthese von Sulfanilamid. Interpretation der IR-Spektren. Die Reaktionsschritte. Acetanilid. Acetanilid. N-H (s). Acetanilid. C-H (s). N-H (s). Acetanilid. C-H (s). N-H (s). C=O (s). Schritt 1. Reaktion von Acetanilid mit Chlorsulfonsäure. p-Acetamidobenzoylsulfonylchlorid.

avian
Download Presentation

Synthese von Sulfanilamid

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. Synthese von Sulfanilamid Interpretation der IR-Spektren

  2. Die Reaktionsschritte

  3. Acetanilid

  4. Acetanilid N-H (s)

  5. Acetanilid C-H (s) N-H (s)

  6. Acetanilid C-H (s) N-H (s) C=O (s)

  7. Schritt 1 Reaktion von Acetanilid mit Chlorsulfonsäure

  8. p-Acetamidobenzoylsulfonylchlorid Verschiebung von N-H und C-H durch zusätzlichen Substituenten S-O neu

  9. p-Acetamidobenzoylsulfonylchlorid N-H (s)

  10. p-Acetamidobenzoylsulfonylchlorid N-H (s) C-H (s)

  11. p-Acetamidobenzoylsulfonylchlorid C=O (s) N-H (s) C-H (s)

  12. p-Acetamidobenzoylsulfonylchlorid C=O (s) N-H (s) S=O (s)asym C-H (s) S=O (s)sym

  13. Schritt 2 Substitution des Chloratoms mit einer Aminogruppe

  14. p-Acetamidobenzoylsulfonylamid S-N neu N-H zusätzlich

  15. p-Acetamidobenzoylsulfonylamid

  16. p-Acetamidobenzoylsulfonylamid N-H (s)

  17. p-Acetamidobenzoylsulfonylamid N-H (s) C-H (s)

  18. p-Acetamidobenzoylsulfonylamid N-H (s) C=O (s) C-H (s)

  19. p-Acetamidobenzoylsulfonylamid N-H (s) C=O (s) S=O (s)asym S=O (s)sym C-H (s)

  20. p-Acetamidobenzoylsulfonylamid S-N (s) N-H (s) C=O (s) S=O (s)asym S=O (s)sym C-H (s)

  21. Schritt 3 Abbau der Schutzgruppe

  22. Sulfanilamid N-H neu C=O verschwindet

  23. Sulfanilamid

  24. Sulfanilamid N-H (s)

  25. Sulfanilamid KeinC=O N-H (s) C-H (s)

  26. Sulfanilamid N-H (d) (C)-NH N-H (s) C-H (s)

  27. Sulfanilamid N-H (d) (C)-NH N-H (d) (S)-NH N-H (s) C-H (s)

  28. Sulfanilamid N-H (d) (C)-NH S=O (s)asym N-H (d) (S)-NH N-H (s) S=O (s)sym C-H (s)

  29. Sulfanilamid S-N (s) N-H (d) (C)-NH S=O (s)asym N-H (d) (S)-NH N-H (s) S=O (s)sym C-H (s)

More Related