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Common Amides. Amides. O R-C NH 2 Alkanoamide. Formamide. O H-C NH 2 Methanoamide. Acetamide. O CH 3 -C NH 2 Ethanoamide. Amides. O CH 3 -CH 2 -C
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Amides • O • R-C • NH2 • Alkanoamide
Formamide • O • H-C • NH2 • Methanoamide
Acetamide • O • CH3-C • NH2 • Ethanoamide
Amides • O • CH3-CH2-C • NH2 • Propanoamide
Amides • O • -C • NH2 • Benzoamide
N-methylbenzoamide • O • -C • NH • CH3
Add Acids & Amines • O • R-C-OH + :NH3 • O • R-C-O- + NH4+
Add Acids & Amines • O • R-C-OH + :NH3
Dehydration of AmS • O • R-C-O- + NH4+ • O • R-C-NH2 + H2O Heat
Dehydration of AmS • O • R-C-NH2 + H2O
Add Acids & Amines • O • R-C-OH + :NH3 • O • R-C-NH2+ H2O
Dehydrating Agents • H2SO4 • P2O5
Acetic acid + Met amine • O • H3C-C-OH + CH3NH2 • O • H3C-C-O- H3NCH3+
N-methylacetamide • O • H3C-C-O- H3NCH3+ • O CH3 • H3C-C-NH+ H2O heat
Drill: • Draw the organic reactant; then, draw & name the organic product of the dehydration of propanoamide.
Esters + Amines • O • R1-C-O-R2 • + • :NH3
Amides + Alcohols • O • R1-C-NH2 • + • R2-OH
Methyl benzoate + A • O • -C-O-CH3 • + • :NH3
Benzoamide & MeOH • O • -C-NH2 • + • HO-CH3
Anhydrides + Amines • O O • R1-C-O-C-R2 • + • :NH3
Amides + Acids • O • R1-C-NH2 • O + • R2-C-OH
AA + HDA • O O • n HO-C-(CH2)4-C-OH • + • n H2N-(CH2)6-NH2 -water
Nylon 66 • O O • -(-C-(CH2)4-C • NH • -(HN-(CH2)6 n
6-aminohexanoic acid • O • x HO-C-(CH2)5-NH2 -water
Nylon 6 • O • x -(-(CH2)5-C-NH-)-
COOH + COOH H2N H2N
C=O + H2O C O HN HN
Making Nitriles • O • R-C-NH2 Heat Dehydration Dehydrate amides
Nitrile + Water • R-C-N: + H2O
CommonNitriles • R-C=N
Acetonitrile • CH3-C=N
Hydrogen Cyanide • H-C=N
Benzonitrile • -C=N