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Ethanol: A Safety Perspective. Renewable Fuels Association “The Voice of the Ethanol Industry” For over 25 years September 2009. Renewable Fuels Association.
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Ethanol: A Safety Perspective Renewable Fuels Association “The Voice of the Ethanol Industry” For over 25 years September 2009
Renewable Fuels Association • National Trade Association for the domestic ethanol industry promoting policy, regulations, research and development for the industry. • History of the Association • Organized in 1981 • Ethanol Producers constitute the Board of Directors • Representing majority of the domestic production • Leader in legislative and technical efforts of industry
United States Transportation Fuels • Gasoline Market 140 billion gallons / year • 160,000 retail fuel stations • Current Ethanol domestic production capacity of 11.5 billion gallons/ year • 190+ plants operating in 25 states • 75% of nation’s gasoline is E10 • E85- ~150 million gallons per year • 2,100 retail fuel pumps
Ethanol as a Fuel & Fuel Additive • E10 (10% ethanol by volume) • Approved for use in all vehicles and engines • ~98% of ethanol consumed as E10 • E85 (70-85% ethanol by volume) • For use in flex-fuel vehicles (FFVs) only • <2% of ethanol consumed as E85 • Mid-level blends (20, 30, 40% ethanol by volume) • For use in FFVs only • Dispensed by “blender pumps” (<250 stations)
The Ethanol Production Process Basic ingredients: Cereal Grains + water + heat + enzymes + yeast 1 Bushel of #2 Yellow Dent Corn produces: 2.7 Gallons of 200 Proof Ethanol 17 Pounds of Distillers Dried Grains 17 Pounds of Carbon Dioxide
Production Hazards Identified • Flammable Liquids • Ethanol • Denaturant, typically Natural Gasoline, Unleaded Gasoline • Grain Handling • Corn • Dust Collection • Process Chemicals • Acids/ Caustics/ Surfactants
Ethanol Plant Grain Handling • Inbound feedstock to the Plant • Corn • Sorghum/ Milo • Typical storage • Silo • Inbound Truck and Railcar • Dust Collection Systems • Hammermill area, grain is pulverized and water added immediately thereafter
Fuel Ethanol Properties • Content: Fuel, 98% Ethanol, 2% Denaturant: Natural Gasoline, Unleaded, Naphtha • Characteristics • Boiling Point: 78°C • Vapor Pressure: 44@ 20°C • Completely miscible with water • MSDS • Polar Solvent- must have Alcohol Resistant type of foam • E85 very similar to this product, higher gasoline %
Fuel Ethanol Use • Midwest gasoline blended at all octane levels • Traditional Markets • Reformulated Gasoline • MTBE replacement • Western States • Oregon 10% mandate • California moving from 6% to 10% blends • Southeast States • Effort to increase ethanol blended with conventional gasoline
Fuel Ethanol Transportation • Rail Transportation • DOT 111A 30k gallon capacity • Truck Transportation • MC306/ DOT406 Transport Trucks • Barge Transportation • Mississippi, Ohio, Missouri, Illinois, Columbia • 10k, 15k barrel inland capacity, Intercoastal barges • Pipeline interest • Quality, Compatibility Research • Matter of “when”, not “if”.
The Virtual Pipeline • Ethanol in Unit Trains • “Ethanol Express” • Shipment volumes ~3 million gallons • Single trains consisting of 65, 75, 95 ethanol cars • Origination in Midwest- Destination all coasts • Major build out of loading and landing locations • #1 Hazmat on rail, less than 2% of all rail shipments
Biofuels in the Pipeline • KinderMorgan’s Central Florida Pipeline • Pipeline distance of 105 miles • Commercial shipments of Fuel Ethanol • Gasoline • KinderMorgan’s Plantation Pipeline • B5 Shipments • 95% Diesel Fuel/ 5% Biodiesel fuel blend
Today’s Terminaling System • 1352 terminals in US • Petroleum and Chemicals • Known conversion techniques • Port terminals handling imports and domestic product • Imported product is denatured immediately upon offload • Rail access improvements • Continued build of unit train loading and landing stations • #1 Hazmat on Rail, still less than 2% of total rail shipments
Recognizing Fuel Ethanol on the move…. • UN 1987 used for all transportation for E95 • Ethanol content >95% • UN 3475 used for all transportation for E85 • Ethanol content >10%, <94% • UN 1993 used for denaturant transportation • Hydrocarbon only designation, Natural Gasoline, Gasoline, Naphtha • UN 1203 used for ethanol/ gasoline blends E10 • Ethanol content <10%
Fuel Ethanol, UN 1987 Location • Plant Storage Tanks • Plant Loading Racks • Trucks/ Railcars/ Barges in transit • Petroleum Terminals • Petroleum Loading Racks blend Ethanol • 10% Ethanol • 90% Unleaded Gasoline • Placard UN 1203 • Headed to Retail Gas Stations
Public and Private Industry coming together to provide much needed emergency response information. • Founding Members: RFA, ILTA, IAFC, Ansul, Williams Fire and Hazard Control, Industrial Fire World Ethanol Emergency Response information available: www.ethanolresponse.com
Complete Training program available: Foam Selection video, Responding to Ethanol Incidents, and Training Modules with instructors guide. May 14, 2007 Baltimore Maryland
RFA Plant and Employee Safety Committee • Health, Safety and Environmental Professionals from Production Facilities • Website for safety being developed: www.ethanolrfa.org • Focus on sharing “best practices” • Promote regulatory compliance • DOT • OSHA • EPA • TTB (formerly the ATF) • DHS (Homeland Security)
One Massachusetts Avenue NW, Suite 820 Washington, DC 20001 P: 202.289.3835 | www.EthanolRFA.org | F: 202.289.7519 © 2008