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Functional Groups

Functional Groups. Functional Groups. Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity. Organic halides: a hydrogen is replaced by a halogen fluoro -, chloro -, bromo -, iodo - 2-iodobutane.

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Functional Groups

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  1. Functional Groups

  2. Functional Groups Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity.

  3. Organic halides: a hydrogen is replaced by a halogenfluoro-, chloro-, bromo-, iodo-2-iodobutane

  4. Organic halides: a hydrogen is replaced by a halogenfluoro-, chloro-, bromo-, iodo-2,4-dibromo-1-hexene

  5. Organic halides: a hydrogen is replaced by a halogenfluoro-, chloro-, bromo-, iodo-1-bromo-2-chlorobenzene

  6. Alcohols & phenols: contain the hydroxyl group (-OH)alcohols: at least 1 H on a hydrocarbon is replaced by OHphenols: at least 1 H on an aromatic ring is replaced by OH2-propanol

  7. Alcohols & phenols: contain the hydroxyl group (-OH)alcohols: at least 1 H on a hydrocarbon is replaced by OHphenols: at least 1 H on an aromatic ring is replaced by OH3-methyl-1-butanol

  8. Alcohols & phenols: contain the hydroxyl group (-OH)alcohols: at least 1 H on a hydrocarbon is replaced by OHphenols: at least 1 H on an aromatic ring is replaced by OH1,2-butanediol

  9. ethers:compounds in which an O atom is bonded to 2 organic groups: -C-O-C-methoxymethane (dimethyl ether)

  10. ethers:compounds in which an O atom is bonded to 2 organic groups: -C-O-C-methoxypropane (methyl propyl ether)

  11. ethers:compounds in which an O atom is bonded to 2 organic groups: -C-O-C-methoxybenzene (methyl phenyl ether)

  12. Carboxylic acids:compounds that contain the carboxyl group (general formula is R-COOH)butanoic acid

  13. Carboxylic acids:compounds that contain the carboxyl group (general formula is R-COOH)ethanoic acid

  14. Carboxylic acids:compounds that contain the carboxyl group (general formula is R-COOH)3-methylpentanoic acid

  15. Carboxylic acids:compounds that contain the carboxyl group (general formula is R-COOH)benzoic acid

  16. amines:derivatives of ammonia (NH3) in which 1 or more H atoms are replaced by organic groups (alkyl or aryl groups) ammonia

  17. amines:derivatives of ammonia (NH3) in which 1 or more H atoms are replaced by organic groups (alkyl or aryl groups)methylamine

  18. amines:derivatives of ammonia (NH3) in which 1 or more H atoms are replaced by organic groups (alkyl or aryl groups)trimethylamine

  19. amines:derivatives of ammonia (NH3) in which 1 or more H atoms are replaced by organic groups (alkyl or aryl groups)2-aminobutane

  20. amines:derivatives of ammonia (NH3) in which 1 or more H atoms are replaced by organic groups (alkyl or aryl groups)1-amino-3-propylcyclohexane

  21. *aniline:the simplest aromatic amineaniline

  22. *aniline:the simplest aromatic amine3,5-dichloroaniline Naming it “aniline” make this carbon #1 by definition

  23. *aniline:the simplest aromatic amineN,N-dimethylaniline

  24. Summary of IUPAC rules for naming organic compounds • IUPAC: International Union of Pure and Applied Chemistry • International, non-governmental organization that is best known for its system of nomenclature, which is now recognized as the world authority in this field.

  25. Rule #1: Identify the longest chain of carbon atoms a) The longest chain of carbon atoms gives the stem/root of the name as shown in the table below:

  26. Rule #1: Identify the longest chain of carbon atoms b) If two chains have equal lengths, pick the one with more branch points.

  27. Rule #2: Number the carbons in the main chain Number chain to minimize the position/number of the following in order of priority: • thing you’re naming the compound after (double bond if alkene; -OH group if alcohol, etc) • note: for multiple double bonds -diene, -triene, -tetraene • first branch/substituent group • If both ends have the same first branching number, then number chain to minimize position of second branch (and then third and so on). • if still in need of a tie breaker, minimize # of substituent group that comes first alphabetically Note: in cyclic and aromatic (benzene derivatives) compounds, no number needed if only one substituent.

  28. Rule #3: Identify the functional group and attach appropriate suffix • Note: the name for the stem/root is derived from the longest carbon chain, which may include the carbon of the functional group. Indicating position of the functional group: shown by a number inserted before the functional group ending. The number refers to the carbon atom to which the functional group is attached when the chain is numbered starting at the end that will give the smallest number to the group.

  29. Rule #4: Identify the side chains or substituent groupsAssign number of carbon at point of attachment.

  30. Rule #5: Assemble name as a single word  #, substituent, root, suffix • List substituents alphabetically (i.e. butyl- before methyl-) • If multiples of one substituent are present: “di-,” “tri-,” “tetra,” etc. • Note: “di-,” “tri-,” “tetra,” etc. aren’t part of alphabetical name (triethyl-before dimethyl-) • punctuation: commas between numbers; hyphens between numbers and letters; merged into one word (exception: acid = word #2 for carboxylic acids)

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