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Functional Groups. Organic Reactions. HALOGEN SUBSTITUTON REACTION. H. H. H. H. Cl. C. Cl. Halogen Molecule. Hydracid. Hydrocarbon. Halocarbon. HALOGEN SUBSTITUTON REACTION. H. H. H. H. H. H. H. +. →. +. C. C. Cl. Cl. Cl. H. Cl. CH 4. +. Cl 2. →. CH (4-1) Cl.
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FunctionalGroups OrganicReactions
HALOGEN SUBSTITUTON REACTION H H H H Cl C Cl Halogen Molecule Hydracid Hydrocarbon Halocarbon
HALOGEN SUBSTITUTON REACTION H H H H H H H + → + C C Cl Cl Cl H Cl CH4 + Cl2 → CH(4-1)Cl CH3Cl + HCl → Chlorine Molecule Hydrochloric Acid Chloromethane Methane + +
HALOGEN SUBSTITUTON REACTION H H Cl Cl H H Cl C Cl- 2Halogen Molecules Halocarbon Disubstituted 2Hydracids Hydrocarbon
HALOGEN SUBSTITUTON REACTION Cl H H H H H H + → + C C Cl 2Cl Cl 2H Cl CH4 + 2Cl2 → CH(4-2)Cl CH2Cl2 + 2HCl 2 Hydrochloric Acid 2 Chlorine Molecule Dichloro methane → Methane + +
HALOGEN SUBSTITUTON REACTION • Foreveryhalogensubstitutionyouneed: • Only 1HydrocarbonMoleculeforallthesubstitutions as long as it has enoughHydrogens • 1 HalogenMoleculewith 2 atoms of thesamehalogen
HALOGEN SUBSTITUTON REACTION • Foreveryhalogensubstitutionyou produce: • Only 1 HalocarbonMoleculewithallthesubstitutions. • 1 Hydrogenatomless and 1 Halogenatom more • 1 HydracidMolecule of thatHalogen
HALOGEN ADDITION REACTION H H H H C C Cl Cl Halogen Molecule Disubstituted Halocarbon Unsaturted Hydrocarbon
HALOGEN ADDITION REACTION H H H H H H H H → + Cl C C Cl C C Cl Cl C2H4Cl2 C2H4 + Cl2 → → Chlorine Molecule Dichloroethane Ethene +
HALOGEN ADDITION REACTION • Foreveryhalogenadditionyouneed: • Only 1UnsaturatedHydrocarbonMoleculeforalltheadditions as long as it has enoughDoubleor Triple bonds • 1 HalogenMoleculewith 2 atoms of thesamehalogen
HALOGEN ADDITION REACTION • Foreveryhalogenadditionyou produce: • Only 1 HalocarbonMoleculewithalltheadditions. • 2 Halogenatom more
Namethe Halogen Branches Fluorine= Fluoro Chlorine= Chloro Bromine= Bromo Iodine= Iodo NamingHalocarbons Namethe Biggest Hydrocarbon Chain Select and Numberthe Biggest Hydrocarbon Chain Namethe Alkyl Branches Arrangethe Branches in Alphabetical Order 2 4 PERFECT! Cl Br CH3 C C 3 CH3 CH3 1 5 CH3 Cl 4 Carbons 5 Carbons 4 Carbons Pentane 2,3-dichloro 2-bromo 3-methyl =
ALCOHOLS • An alcohol isanorganiccompound in which a hydroxylgroupreplaces a hydrogenatom of a hydrocarbon. • General Formula R-OH • Nameitthesame as alkanesbutchangetheending -e for –ol and addthe position of the OH. • Ifthere are more thanone OH, don’teliminatethe -e, puttheir positions, and put a prefix (d,tri,tetra, etc.)
AMINES • An amine isanorganiccompoudthatcontainnitrogenatomsbondedtocarbonatoms in rings. • General Formula R-NH2 • Nameitthesame as alcoholsbutchangetheending -olfor –amine and thehydrocarbonpartisnamedlike a branch (exceptfor more thanone NH2).
ETHERS • Anetherisanorganiccompoundcontaininganoxygenatombondedtotwocarbonatoms. • General Formula R-O-R’ • Nameitbynamingbothhydrocarbonchains as branches and addtheendingether