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Hydrocarbons with Functional Groups Alcohols. Alcohols At the conclusion of our time together, you should be able to:. Recognize the functional group and give a characteristic of this organic compound Name the organic compound with this functional group
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AlcoholsAt the conclusion of our time together, you should be able to: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
Functional Groups • A group of covalently bonded elements that when bonded to a carbon chain give it a unique quality. • Compounds with similar functional groups will have similar qualities and properties.
Alcohols • They are organic compounds that are primarily used as disinfectants. • Alcohols have the functional group of –OH. • They have the general formula of R-OH.
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Alcohols are named by adding the suffix -ol. If there is more than one hydroxyl group (-OH), the suffix is expanded to include a prefix that indicates the number of hydroxyl groups present (-diol, -triol, etc.). The position of the hydroxyl group on the parent chain is indicated by placing the number corresponding to the location on the parent chain directly in front of the base name. How to Name Alcohols
The hydroxyl group takes precedence over alkyl groups and halogen substituents, as well as double bonds, in the numbering of the parent chain. If there is a choice in numbering after these rules are followed, the parent chain is numbered to give the substituents the lowest number. How to Name Alcohols
Examples of Naming Alcohols A Primary Alcohol – (-OH attached to an end carbon that is attached to 1 other carbon) Ethanol – drinking alcohol
Examples of Naming Alcohols A Secondary Alcohol – (-OH attached to a middle carbon that has 2 other carbon bonds) 2-propanol
Examples of Naming Alcohols A Tertiary Alcohol – (-OH attached to a middle carbon that has 3 other carbon bonds) 1,1-dimethylethanol (no) 2-methyl-2-propanol or 2-methylpropane-1-ol
More Examples of Naming Alcohols 1,2,3-propantriol Propane-1,2,3-triol benzenol phenol
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AlcoholsLet’s see if you can: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
EthersAt the conclusion of our time together, you should be able to: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
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Ethers • They are organic compounds that are primarily used as anesthetics. • Ethers have the functional group of –O– in the middle of the carbon chain. • They have the general formula of R-O-R’.
Examples of Naming Ethers • Name the chains as alkyl groups • Put them in alphabetical order • End with ether.
Examples of Naming Ethers • Name the chains as an alkyl groups • Put them in alphabetical order • (ethyl, can’t be propyl, why?) • (at 1 and 1 there are methyl groups) • End with ether. • 1,1-dimethyl ethylmethyl ether
EthersLet’s see if you can: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
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Functional Groups • A group of covalently bonded elements that when bonded to a carbon chain give it a unique quality. • Compounds with similar functional groups will have similar qualities and properties.
Organic AcidsAt the conclusion of our time together, you should be able to: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
Organic Acids • They are an organic compound that is primarily used as protection for fruits and vegetables. • Organic acids have the functional group of –COOH on the end of the carbon chain. This is called the carboxyl group. • They have the general formula of R-COOH.
Examples of Naming Organic Acids • Name the R chain and include the C of the carboxyl group • End with –oic acid
Examples of Naming Organic Acids • Name the R chain and include the C of the carboxyl group (methane) • End with –oic acid • methanoic acid
Chemical Compound Quiz Acetylsalicylic acid helps cure aches and pains. What is the common name? Aspirin
Organic AcidsLet’s see if you can: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
Exit Quiz: Carboxylic Acids O || HO-C-C=O | OH Ethanoic acid What’s the formula? Is it like HC2H3O2? Acetic acid!! ethane-1,2-dioic acid or ethandioic acid
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Exit Quiz: Carboxylic Acids 2-methylpropanoic acid
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KetonesAt the conclusion of our time together, you should be able to: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
Ketones • These are organic compounds that are primarily used as solvents. • Ketones have the functional group of =O somewhere in the middle of the carbon chain.
Examples of Naming Ketones • Name the hydrocarbon chain. • End with –one. • Give the number of the carbon to which the ketone group is attached. • 2-propanone • Common name – acetone.
KetonesLet’s see if you can: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
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Examples of Naming Ketones • Name the hydrocarbon chain. • End with –one. • Give the number of the carbon to which the ketone group is attached. • 4-methyl-2-pentanone
AldehydesAt the conclusion of our time together, you should be able to: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
Aldehydes • These are organic compounds that are primarily used as preservatives. • Aldehydes have the functional group of =O on the end of the carbon chain.
Examples of Naming Aldehydes • Name the hydrocarbon chain. • End with –al. • methanal • Common name – formaldehyde.
Examples of Naming Aldehydes • Name the hydrocarbon chain. • End with –al. • benzenal (benzaldehyde)
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AldehydesLet’s see if you can: • Recognize the functional group and give a characteristic of this organic compound • Name the organic compound with this functional group • Draw this organic compound with this functional group
Exit Quiz of Drawing Aldehydes: 4-ethylhexanal CH3-CH2-CH-CH2-CH2-CH=O | CH3-CH2